Next Article in Journal
Antioxidant Activity of a Series of FluorinatedPyrano-nucleoside Analogues of N4-benzoyl Cytosine andN6-benzoyl Adenine
Previous Article in Journal
Non-Open Access and Its Adverse Impact on International Journal of Molecular Sciences
Article Menu

Export Article

Open AccessCommunication
Int. J. Mol. Sci. 2007, 8(7), 688-694; doi:10.3390/i8070688

Calorimetric and Computational Study of Enthalpy of Formation of Diperoxide of Cyclohexanone

Área de Fisicoquímica, Facultad de Ciencias Exactas, Naturales y Agrimensura, Universidad Nacional del Nordeste, Corrientes, Argentina
INIFTA, Theoretical Chemistry Division, Suc. 4, C.C. 16, La Plata 1900, Buenos Aires, Argentina
CEQUINOR, Chemistry Department, Faculty of Exact Sciences and Engineering Faculty, La Plata National University, C.C. 962, La Plata 1900, Buenos Aires, Argentina
Author to whom correspondence should be addressed.
Received: 27 February 2007 / Revised: 18 July 2007 / Accepted: 18 July 2007 / Published: 19 July 2007
(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)
View Full-Text   |   Download PDF [163 KB, uploaded 19 June 2014]   |  


A thermochemical rather simple experimental technique is applied to determinethe enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented withsuitable theoretical calculations at the semiempirical and ab initio levels. A particularsatisfactory agreement between both ways is found for the ab initio calculation at the 6-311G basis This set level. Some possible extensions of the present procedure are pointedout. View Full-Text
Keywords: tetroxane; diperoxide; enthalpy of formation; heat. tetroxane; diperoxide; enthalpy of formation; heat.

This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Romero, J.M.; Bustillo, S.; Maisuls, H.E.R.; Jorge, N.L.; Vara, M.E.G.; Castro, E.A.; Jubert, A.H. Calorimetric and Computational Study of Enthalpy of Formation of Diperoxide of Cyclohexanone. Int. J. Mol. Sci. 2007, 8, 688-694.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics



[Return to top]
Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top