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Int. J. Mol. Sci. 2007, 8(7), 593-605; doi:10.3390/i8070593

On the Extraction of Aromatic Compounds from Hydrocarbons by Imidazolium Ionic Liquids

Laboratory of Molecular Catalysis, Institute of Chemistry, UFRGS, Av. Bento Gonçalves, 9500 Porto Alegre 91501-970 RS Brazil
PETROBRAS Research Center - CENPES-PETROBRAS, Hydrorefining and Special Processes, Av. Prof. Horácio Macedo, 950 Ilha do Fundão, Rio de Janeiro, 21941-598 RJ, Brazil
Author to whom correspondence should be addressed.
Received: 12 June 2007 / Revised: 22 June 2007 / Accepted: 22 June 2007 / Published: 2 July 2007
(This article belongs to the Special Issue Ionic Liquids)
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The liquid-liquid equilibrium for the ternary system formed by n-octane andaromatic (alkylbenzenes) and heteroaromatic compounds (nitrogen and sulfur containingheterocyles) and 1-alkyl-3-methylimidazolium ionic liquids (ILs) associated with variousanions has been investigated. The selectivity on the extraction of a specific aromaticcompound is influenced by anion volume, hydrogen bond strength between the anion andthe imidazolium cation and the length of the 1-methyl-3-alkylimidazolium alkyl side chain.The interaction of alkylbenzenes and sulfur heterocyles with the IL is preferentially throughCH-π hydrogen bonds and the quantity of these aromatics in the IL phase decreases withthe increase of the steric hindrance imposed by the substituents on the aromatic nucleus. Inthe case of nitrogen heterocycles the interaction occurs preferentially throughN(heteroaromatic)-H(imidazolium) hydrogen bonds and the extraction process is largelycontrolled by the nitrogen heterocycle pKa. Competitive extraction experiments suggestthat benzene, pyridine and dibenzothiophene do not compete for the same hydrogen bondsites of the IL. View Full-Text
Keywords: ionic liquid; extraction; fuel; aromatics; hydrogen bonds. ionic liquid; extraction; fuel; aromatics; hydrogen bonds.

This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Cassol, C.C.; Umpierre, A.P.; Ebeling, G.; Ferrera, B.; Chiaro, S.S.X.; Dupont, J. On the Extraction of Aromatic Compounds from Hydrocarbons by Imidazolium Ionic Liquids. Int. J. Mol. Sci. 2007, 8, 593-605.

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