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Int. J. Mol. Sci. 2016, 17(5), 670; doi:10.3390/ijms17050670

Investigation of Ternary Mixtures Containing 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)azanide, Ethylene Carbonate and Lithium Bis(trifluoromethanesulfonyl)azanide

1
Karlsruher Institut für Technologie (KIT), Institut für Angewandte Materialien—Werkstoffkunde (IAM-WK), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
2
Institut für Mikrosystemtechnik, Universität Freiburg, Georges-Köhler-Allee 102, 79110 Freiburg, Germany
*
Author to whom correspondence should be addressed.
Academic Editors: Andreas Taubert and Peter Hesemann
Received: 1 March 2016 / Revised: 18 April 2016 / Accepted: 25 April 2016 / Published: 4 May 2016
(This article belongs to the Special Issue Ionic Liquids 2016 and Selected Papers from ILMAT III)
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Abstract

Temperature-dependent viscosity, conductivity and density data of ternary mixtures containing 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)azanide (EMIM-TFSA), ethylene carbonate (EC), and lithium bis(trifluoromethanesulfonyl)azanide (Li-TFSA) were determined at atmospheric pressure in the temperature range of 20 to 80 °C. Differential scanning calorimetry (DSC) measurements were performed to characterize phase conditions of the mixtures in a temperature range of −120 to +100 °C. The viscosity data were fitted according to the Vogel-Fulcher-Tammann-Hesse (VFTH) equation and analyzed with the help of the fractional Walden rule. In this study, fundamental physicochemical data about the mixtures are provided and discussed as a basis for structure-property relationship calculations and for potential use of those mixtures as electrolytes for various applications. View Full-Text
Keywords: ionic liquid; conductivity; density; viscosity; electrolytes ionic liquid; conductivity; density; viscosity; electrolytes
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Hofmann, A.; Migeot, M.; Arens, L.; Hanemann, T. Investigation of Ternary Mixtures Containing 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)azanide, Ethylene Carbonate and Lithium Bis(trifluoromethanesulfonyl)azanide. Int. J. Mol. Sci. 2016, 17, 670.

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