Int. J. Mol. Sci. 2013, 14(1), 714-806; doi:10.3390/ijms14010714
Article

Molecular Eigensolution Symmetry Analysis and Fine Structure

1,* email and 2email
Received: 3 September 2012; in revised form: 26 November 2012 / Accepted: 27 November 2012 / Published: 4 January 2013
(This article belongs to the Special Issue Molecular Symmetry)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Spectra of high-symmetry molecules contain fine and superfine level cluster structure related to J-tunneling between hills and valleys on rovibronic energy surfaces (RES). Such graphic visualizations help disentangle multi-level dynamics, selection rules, and state mixing effects including widespread violation of nuclear spin symmetry species. A review of RES analysis compares it to that of potential energy surfaces (PES) used in Born-Oppenheimer approximations. Both take advantage of adiabatic coupling in order to visualize Hamiltonian eigensolutions. RES of symmetric and D2 asymmetric top rank-2-tensor Hamiltonians are compared with Oh spherical top rank-4-tensor fine-structure clusters of 6-fold and 8-fold tunneling multiplets. Then extreme 12-fold and 24-fold multiplets are analyzed by RES plots of higher rank tensor Hamiltonians. Such extreme clustering is rare in fundamental bands but prevalent in hot bands, and analysis of its superfine structure requires more efficient labeling and a more powerful group theory. This is introduced using elementary examples involving two groups of order-6 (C6 and D3~C3v), then applied to families of Oh clusters in SF6 spectra and to extreme clusters.
Keywords: symmetry; molecular dynamics; tunneling; level clusters
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MDPI and ACS Style

Harter, W.G.; Mitchell, J.C. Molecular Eigensolution Symmetry Analysis and Fine Structure. Int. J. Mol. Sci. 2013, 14, 714-806.

AMA Style

Harter WG, Mitchell JC. Molecular Eigensolution Symmetry Analysis and Fine Structure. International Journal of Molecular Sciences. 2013; 14(1):714-806.

Chicago/Turabian Style

Harter, William G.; Mitchell, Justin C. 2013. "Molecular Eigensolution Symmetry Analysis and Fine Structure." Int. J. Mol. Sci. 14, no. 1: 714-806.

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