Tetrachloridocuprates(II)—Synthesis and Electron Paramagnetic Resonance (EPR) Spectroscopy
Abstract
:1. Introduction
2. Results and Discussion
3. Experimental Section
3.1. Chemicals
3.2. Preparation
3.3. Bis(hexadecyltrimethylammonium) Tetrachloridocuprate(II), (C16H33Me3N)2[CuCl4] (1)
3.4. Bis(tetradecyltrimethylammonium) Tetrachloridocuprate(II), (C14H29Me3N)2[CuCl4] (2)
3.5. Bis(tetrabutylammonium) Tetrachloridocuprate(II), (Bu4N)2[CuCl4] (3)
3.6. Bis(benzyltriethylammonium) Tetrachloridocuprate(II), (BzlEt3N)2[CuCl4] (4)
4. Conclusions
References
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Compound | g║ | g┴ | gav |
---|---|---|---|
(C16H33Me3N)2[CuCl4] (1) | 2.365 ± 0.005 | 2.145 ± 0.005 | 2.218 ± 0.005 |
(C14H29Me3N)2[CuCl4] (2) | 2.366 ± 0.005 | 2.141 ± 0.005 | 2.216 ± 0.005 |
(Bu4N)2[CuCl4] (3) | 2.394 ± 0.005 | 2.081 ± 0.005 | 2.185 ± 0.005 |
(BzlEt3N)2[CuCl4] (4) | 2.424 ± 0.005 | 2.089 ± 0.005 | 2.200 ± 0.005 |
(BuPy)2[Cu/ZnCl4] [33] | 2.300 ± 0.005 | 2.070 ± 0.005 | 2.147 ± 0.005 |
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Winter, A.; Zabel, A.; Strauch, P. Tetrachloridocuprates(II)—Synthesis and Electron Paramagnetic Resonance (EPR) Spectroscopy. Int. J. Mol. Sci. 2012, 13, 1612-1619. https://doi.org/10.3390/ijms13021612
Winter A, Zabel A, Strauch P. Tetrachloridocuprates(II)—Synthesis and Electron Paramagnetic Resonance (EPR) Spectroscopy. International Journal of Molecular Sciences. 2012; 13(2):1612-1619. https://doi.org/10.3390/ijms13021612
Chicago/Turabian StyleWinter, Alette, André Zabel, and Peter Strauch. 2012. "Tetrachloridocuprates(II)—Synthesis and Electron Paramagnetic Resonance (EPR) Spectroscopy" International Journal of Molecular Sciences 13, no. 2: 1612-1619. https://doi.org/10.3390/ijms13021612