Next Article in Journal
The Chitinolytic Activities of Streptomyces sp. TH-11
Previous Article in Journal
Erwinia mallotivora sp., a New Pathogen of Papaya (Carica papaya) in Peninsular Malaysia
Article Menu

Export Article

Open AccessArticle
Int. J. Mol. Sci. 2011, 12(1), 46-55; https://doi.org/10.3390/ijms12010046

Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization

Department of Osteology, The First Affiliated Hospital of Fujian Medical University, Fuzhou 350005, China
*
Author to whom correspondence should be addressed.
Received: 31 October 2010 / Revised: 1 December 2010 / Accepted: 13 December 2010 / Published: 27 December 2010
(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)
Full-Text   |   PDF [386 KB, uploaded 19 June 2014]

Abstract

Flexible and asymmetric ligand L [L = 1-((pyridin-3-yl)methyl)-1H-benzotriazole], is used as a basic backbone to construct complicated metal-organic frameworks. Two new polymers, namely, [Ag2(L)2(NO3)2]n (1) and [Ag(L)(ClO4)]n (2), were synthesized and characterized by X-ray structure analysis and fluorescent spectroscopy. The complex 1 gives an “S” type double helical conformation, whereas complex 2 exhibits a 1D zigzag configuration. Different anions affect the silver coordination geometry and crystal packing topology. View Full-Text
Keywords: flexible and asymmetric ligand; double helical conformation; zigzag configuration flexible and asymmetric ligand; double helical conformation; zigzag configuration
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
SciFeed

Share & Cite This Article

MDPI and ACS Style

Chen, P.; Lin, J. Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization. Int. J. Mol. Sci. 2011, 12, 46-55.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top