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Int. J. Mol. Sci. 2011, 12(1), 46-55; doi:10.3390/ijms12010046

Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization

Department of Osteology, The First Affiliated Hospital of Fujian Medical University, Fuzhou 350005, China
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Author to whom correspondence should be addressed.
Received: 31 October 2010 / Revised: 1 December 2010 / Accepted: 13 December 2010 / Published: 27 December 2010
(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)
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Abstract

Flexible and asymmetric ligand L [L = 1-((pyridin-3-yl)methyl)-1H-benzotriazole], is used as a basic backbone to construct complicated metal-organic frameworks. Two new polymers, namely, [Ag2(L)2(NO3)2]n (1) and [Ag(L)(ClO4)]n (2), were synthesized and characterized by X-ray structure analysis and fluorescent spectroscopy. The complex 1 gives an “S” type double helical conformation, whereas complex 2 exhibits a 1D zigzag configuration. Different anions affect the silver coordination geometry and crystal packing topology.
Keywords: flexible and asymmetric ligand; double helical conformation; zigzag configuration flexible and asymmetric ligand; double helical conformation; zigzag configuration
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Chen, P.; Lin, J. Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization. Int. J. Mol. Sci. 2011, 12, 46-55.

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