Next Article in Journal
Optimization of the Culture Medium Composition to Improve the Production of Hyoscyamine in Elicited Datura stramonium L. Hairy Roots Using the Response Surface Methodology (RSM)
Previous Article in Journal
Comparison of TNFα to Lipopolysaccharide as an Inflammagen to Characterize the Idiosyncratic Hepatotoxicity Potential of Drugs: Trovafloxacin as an Example
Article Menu

Export Article

Open AccessArticle
Int. J. Mol. Sci. 2010, 11(11), 4715-4725; doi:10.3390/ijms11114715

Study of Influencing Factors and the Mechanism of Preparing Triazinedithiol Polymeric Nanofilms on Aluminum Surfaces

Northwest Agriculture & Forest University, College of Science, Shaanxi, Yangling 712100, China
*
Author to whom correspondence should be addressed.
Received: 27 September 2010 / Revised: 19 October 2010 / Accepted: 17 November 2010 / Published: 18 November 2010
(This article belongs to the Section Material Sciences and Nanotechnology)
View Full-Text   |   Download PDF [809 KB, uploaded 19 June 2014]   |  

Abstract

Triazinedithiol polymeric nanofilm was prepared on a pure aluminum surface by electrochemical polymerization of AF17N. The mechanism of the process was proposed and electrochemical polymerization parameters were investigated. The triazinedithiol polymeric nanofilm had notable lubricity, high dielectric property and superhydrophobic property due to the allyl and fluoro alkyl groups in the AF17N monomer. The chemical structure of poly (6-(N-allyl-1,1,2,2-tetrahydroperfluorodecyl)amino-1,3,5-triazine-2,4-dithiol monosodium) nanofilm (PAF17) was investigated by analysis of FT-IR spectra and X-ray photoelectron spectroscopy (XPS). The optimal conditions for the preparation process were based on the data of film weight and thickness. The optimal parameters of monomer concentration, electropolymerization time and temperature were 5 mM, 6 min and 15 °C, respectively. The electropolymerization mechanism was a radical polymerization reaction. It is expected that this technique will be applied in industrial fields for aluminum and aluminum alloy to achieve functional surfaces. View Full-Text
Keywords: triazinedithiol; aluminum surface; functional polymeric nanofilm; electropolymerization mechanism triazinedithiol; aluminum surface; functional polymeric nanofilm; electropolymerization mechanism
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Wang, F.; Wang, Y.; Li, Y. Study of Influencing Factors and the Mechanism of Preparing Triazinedithiol Polymeric Nanofilms on Aluminum Surfaces. Int. J. Mol. Sci. 2010, 11, 4715-4725.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top