Microwave-Accelerated or Conventionally Heated Iodination Reactions of Some Aromatic Amines, Using ortho-Periodic Acid as the Oxidant †

doi:10.3390/90700617

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Molecules 2004, 9(7), 617-621; doi:10.3390/90700617

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Microwave-Accelerated or Conventionally Heated Iodination Reactions of Some Aromatic Amines, Using ortho-Periodic Acid as the Oxidant †

Maciej Sosnowski, Lech Skulski* and Katarzyna Wolowik

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, 1 Banacha Street, PL 02-097 Warsaw, Poland

* Author to whom correspondence should be addressed.

Received: 23 April 2004 / Accepted: 8 May 2004 / Published: 30 June 2004

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Abstract: A fast and simple method for the oxidative iodination of some aromatic amines, either under microwave irradiation or conventional heating, is reported, using diiodine and ortho-periodic acid as the oxidant. The reactions were carried out in boiling CH2Cl2 solutions under a reflux condenser. For the microwave assisted reactions, the reaction times were always notably shortened, but the yields were usually less influenced as compared with the conventional method.

Keywords: Monoiodinated arylamines; arylamines; ortho-periodic acid as oxidant; microwave irradiation.

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MDPI and ACS Style

Sosnowski, M.; Skulski, L.; Wolowik, K. Microwave-Accelerated or Conventionally Heated Iodination Reactions of Some Aromatic Amines, Using ortho-Periodic Acid as the Oxidant †. Molecules 2004, 9, 617-621.

AMA Style

Sosnowski M, Skulski L, Wolowik K. Microwave-Accelerated or Conventionally Heated Iodination Reactions of Some Aromatic Amines, Using ortho-Periodic Acid as the Oxidant †. Molecules. 2004; 9(7):617-621.

Chicago/Turabian Style

Sosnowski, Maciej; Skulski, Lech; Wolowik, Katarzyna. 2004. "Microwave-Accelerated or Conventionally Heated Iodination Reactions of Some Aromatic Amines, Using ortho-Periodic Acid as the Oxidant †." Molecules 9, no. 7: 617-621.

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