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Molecules 2002, 7(12), 867-870; doi:10.3390/71200867
Article

Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant

 and *
Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, 1 Banacha Street, PL 02-097 Warsaw, Poland
* Author to whom correspondence should be addressed.
Received: 15 October 2002 / Revised: 11 December 2002 / Accepted: 12 December 2002 / Published: 31 December 2002
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Abstract

A fast and simple method for the oxidative iodination of some aromatic amines, under microwave irradiation, is reported, using diiodine and the the strongly Hbonded urea-hydrogen peroxide addition compound (H2NCONH2···H2O2, UHP) as the oxidant. The reactions were carried out in boiling CHCl3 under a reflux condenser to afford, within 10 minutes, the purified monoiodinated products in 40-80% yields.
Keywords: Monoiodinated arylamines; urea-hydrogen peroxide as oxidant; microwave irradiation Monoiodinated arylamines; urea-hydrogen peroxide as oxidant; microwave irradiation
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Sosnowski, M.; Skulski, L. Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant. Molecules 2002, 7, 867-870.

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