Molecules 2001, 6(3), 258-266; doi:10.3390/60300258
Article

Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides

Received: 24 January 2001; Accepted: 7 February 2001 / Published: 28 February 2001
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The Cu-catalyzed intramolecular CH insertion of phenyliodonium ylide 5b has been investigated at 0° C in the presence of several chiral ligands. Enantioselectivities vary in the range of 38–72 %, and are higher than those resulting from reaction of the diazo compound 5c at 65° C. The results are consistent with a carbenoid mechanism for Cu-catalyzed decomposition of phenyliodonium ylides.
Keywords: Phenyliodonium ylides; CH insertion; Cu-catalysis; asymmetric induction
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MDPI and ACS Style

Müller, P.; Boléa, C. Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides. Molecules 2001, 6, 258-266.

AMA Style

Müller P, Boléa C. Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides. Molecules. 2001; 6(3):258-266.

Chicago/Turabian Style

Müller, Paul; Boléa, Christelle. 2001. "Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides." Molecules 6, no. 3: 258-266.

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