Molecules 2001, 6(3), 244-252; doi:10.3390/60300244
Article

Synthesis of (±)-trans-2,5-Diisopropylborolane

Received: 1 February 2001; Accepted: 3 February 2001 / Published: 28 February 2001
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5-diisopropylborolane (14) was isolated following selective complexation of the cis-2,5-diisopropylborolane (15) with 1-(2-hydroxyethyl)-pyrrolidine.
Keywords: Cyclic hydroboration; diisopropylborolane; complexation
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MDPI and ACS Style

Laschober, G.; Zorzi, M.; Hodgetts, K.J. Synthesis of (±)-trans-2,5-Diisopropylborolane. Molecules 2001, 6, 244-252.

AMA Style

Laschober G, Zorzi M, Hodgetts KJ. Synthesis of (±)-trans-2,5-Diisopropylborolane. Molecules. 2001; 6(3):244-252.

Chicago/Turabian Style

Laschober, Gerhard; Zorzi, Massimo; Hodgetts, Kevin J. 2001. "Synthesis of (±)-trans-2,5-Diisopropylborolane." Molecules 6, no. 3: 244-252.

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