Next Article in Journal
Preparation of Arylthiocyanates Using N,N′-Dibromo-N,N′-bis(2,5-dimethylbenzenesulphonyl) ethylenediamine and N,NDibromo-2,5-dimethylbenzenesulphonamide in the Presence of KSCN as a Novel Thiocyanating Reagent
Previous Article in Journal
Synthesis of Acridine-based DNA Bis-intercalating Agents
Article Menu

Export Article

Open AccessArticle
Molecules 2001, 6(3), 244-252; doi:10.3390/60300244

Synthesis of (±)-trans-2,5-Diisopropylborolane

Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland
*
Author to whom correspondence should be addressed.
Received: 1 February 2001 / Accepted: 3 February 2001 / Published: 28 February 2001
View Full-Text   |   Download PDF [44 KB, uploaded 18 June 2014]   |  

Abstract

The cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5-diisopropylborolane (14) was isolated following selective complexation of the cis-2,5-diisopropylborolane (15) with 1-(2-hydroxyethyl)-pyrrolidine. View Full-Text
Keywords: Cyclic hydroboration; diisopropylborolane; complexation Cyclic hydroboration; diisopropylborolane; complexation
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Laschober, G.; Zorzi, M.; Hodgetts, K.J. Synthesis of (±)-trans-2,5-Diisopropylborolane. Molecules 2001, 6, 244-252.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top