Synthesis of (±)-trans-2,5-Diisopropylborolane
AbstractThe cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5-diisopropylborolane (14) was isolated following selective complexation of the cis-2,5-diisopropylborolane (15) with 1-(2-hydroxyethyl)-pyrrolidine. View Full-Text
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Laschober, G.; Zorzi, M.; Hodgetts, K.J. Synthesis of (±)-trans-2,5-Diisopropylborolane. Molecules 2001, 6, 244-252.
Laschober G, Zorzi M, Hodgetts KJ. Synthesis of (±)-trans-2,5-Diisopropylborolane. Molecules. 2001; 6(3):244-252.Chicago/Turabian Style
Laschober, Gerhard; Zorzi, Massimo; Hodgetts, Kevin J. 2001. "Synthesis of (±)-trans-2,5-Diisopropylborolane." Molecules 6, no. 3: 244-252.