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Molecules 2001, 6(11), 909-914; doi:10.3390/61100909

Synthesis and Crystal Structure Determination of a Nickel(II) Complex of an Acyclic Pentadentate (N5) Mono Schiff Base Ligand

1
Department of Chemistry, Bu-Ali Sina University, Hamadan, Zip Code 65174, Iran
2
Department of Chemistry, UMIST, PO Box 88, Manchester M60 1QD, UK
*
Author to whom correspondence should be addressed.
Received: 19 June 2001 / Revised: 24 September 2001 / Accepted: 22 October 2001 / Published: 31 October 2001
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Abstract

The asymmetrical tripodal tetraamine ligand N[(CH2)3NH2]2[(CH2)2NH2] (ppe) was condensed with 2-acetylpyridine in the presence of nickel(II) ion. In ethanolwater solution the reaction stops after the first stage of condensation, and a new nickel(II) complex of an acyclic pentadentate (N5) mono Schiff base ligand was obtained. X-ray structure analysis of the resulting complex, [Ni(ppe-py)(H2O)](ClO4)2, indicates that condensation with 2-acetylpyridine is at the propylene chain of ppe. The geometry around the nickel ion is distorted octahedral in which the sixth co-ordination group is a solvent molecule.
Keywords: Schiff-base; Acyclic pentadentate ligand; Nickel (II) complex Schiff-base; Acyclic pentadentate ligand; Nickel (II) complex
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Keypour, H.; Salehzadeh, S.; Pritchard, R.G.; Parish, R.V. Synthesis and Crystal Structure Determination of a Nickel(II) Complex of an Acyclic Pentadentate (N5) Mono Schiff Base Ligand. Molecules 2001, 6, 909-914.

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