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Molecules 2000, 5(9), 1068-1079; doi:10.3390/50901068
Review

Recent Advances in the Substitution Reactions of Triorganylstannyl Ions with Aromatic Compounds by the SRN1 Mechanism. Synthetic Applications

,  and *
INFIQC, Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba. Ciudad Universitaria, 5000 Córdoba, Argentina
* Author to whom correspondence should be addressed.
Received: 30 May 2000 / Revised: 18 August 2000 / Accepted: 5 September 2000 / Published: 11 September 2000
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Abstract

A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the synthetic applications of the resulting triorganyl stannyl aryl compounds is made, with their inherent potential to build large molecules through the SRN1 sequence, i.e. ArX→ArSnR3→ArAr, which can be iteratively repeated when appropriately substituted substrates are chosen.
Keywords: stannyl anions; SRN1; Stille reactions stannyl anions; SRN1; Stille reactions
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Córsico, E.F.; Postigo, A.; Rossi, R.A. Recent Advances in the Substitution Reactions of Triorganylstannyl Ions with Aromatic Compounds by the SRN1 Mechanism. Synthetic Applications. Molecules 2000, 5, 1068-1079.

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