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Molecules 2000, 5(9), 1062-1067; doi:10.3390/50901062
Article

Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction

*  and
Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto 390-8621, Japan
* Author to whom correspondence should be addressed.
Received: 14 August 2000 / Accepted: 6 September 2000 / Published: 9 September 2000
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Abstract

An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described.
Keywords: Swern oxidation; vicinal cis-diol; α-diketone; ring-opening; norbornene; pyrazine Swern oxidation; vicinal cis-diol; α-diketone; ring-opening; norbornene; pyrazine
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Kobayashi, T.; Kobayashi, S. Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction. Molecules 2000, 5, 1062-1067.

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