Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties

doi:10.3390/50300451

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Molecules 2000, 5(3), 451-452; doi:10.3390/50300451

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Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties

S. C. Pellegrinet¹, M. T. Baumgartner^2,* and R. A. Spanevello¹

¹ Instituto de Química Orgánica de Síntesis (IQUIOS)- CONICET; Facultad de Ciencias Bioquímicas y Farmacéuticas-U.N.R. Suipacha 531, Rosario (2000), Argentina ² INFIQC - Departamento de Químíca Orgánica, Fac. Ciencias Químicas- U.N.C. Ciudad Universitaria, (5000) Córdoba, Argentina

* Author to whom correspondence should be addressed.

Published: 22 March 2000

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Abstract: Semiempirical calculations were performed to carry out a conformational analysis for carbohydrate-derived dienophiles 1-4. For α,β-unsaturated carbonylic compounds 2-4, a good correlation between Diels-Alder reactivity with calculated values for LUMO energies was observed.

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MDPI and ACS Style

Pellegrinet, S.C.; Baumgartner, M.T.; Spanevello, R.A. Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties. Molecules 2000, 5, 451-452.

AMA Style

Pellegrinet SC, Baumgartner MT, Spanevello RA. Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties. Molecules. 2000; 5(3):451-452.

Chicago/Turabian Style

Pellegrinet, S. C.; Baumgartner, M. T.; Spanevello, R. A. 2000. "Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties." Molecules 5, no. 3: 451-452.

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