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Molecules 2000, 5(3), 451-452; doi:10.3390/50300451
Abstract

Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties

1, 2,*  and 1
1 Instituto de Química Orgánica de Síntesis (IQUIOS)- CONICET; Facultad de Ciencias Bioquímicas y Farmacéuticas-U.N.R. Suipacha 531, Rosario (2000), Argentina 2 INFIQC - Departamento de Químíca Orgánica, Fac. Ciencias Químicas- U.N.C. Ciudad Universitaria, (5000) Córdoba, Argentina
* Author to whom correspondence should be addressed.
Published: 22 March 2000
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Abstract

Semiempirical calculations were performed to carry out a conformational analysis for carbohydrate-derived dienophiles 1-4. For α,β-unsaturated carbonylic compounds 2-4, a good correlation between Diels-Alder reactivity with calculated values for LUMO energies was observed.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Pellegrinet, S.C.; Baumgartner, M.T.; Spanevello, R.A. Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties. Molecules 2000, 5, 451-452.

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