Next Article in Journal
Synthesis of 1-(2'-Deoxy-ß-D-ribofuranosyl)-1H-imidazo[4,5-d]-pyridazine-4,7(5H,6H)-dione: A Potential Building Block for Antisense Applications
Previous Article in Journal
Regioselective Oxidation of 3-Substituted Pyridinium Salts
Molecules 2000, 5(11), 1182-1186; doi:10.3390/51101182
Article

The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products

, *  and
Received: 22 August 2000 / Revised: 5 October 2000 / Accepted: 10 October 2000 / Published: 1 November 2000
Download PDF [29 KB, uploaded 18 June 2014]

Abstract

Treatment of trimethylsilylethynyl(phenyl)iodonium triflate with the potassium salts of some acidic phenols results in the formation of substitution products (O-trimethylsilylethynylphenols and/or O-ethynylphenols), along with sp2C-H insertion products which afford eventually 2-aroxybenzo[b]furans.
Keywords: Alkynyl iodonium salts; ethynyl phenyl ethers; benzo[b]furans Alkynyl iodonium salts; ethynyl phenyl ethers; benzo[b]furans
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote
MDPI and ACS Style

Nikas, S.; Rodios, N.; Varvoglis, A. The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products. Molecules 2000, 5, 1182-1186.

View more citation formats

Related Articles

Article Metrics

Comments

Citing Articles

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert