Molecules 2000, 5(11), 1182-1186; doi:10.3390/51101182
Article

The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products

Spyros Nikas, Nestor Rodios* email and Anastasios Varvoglis
Laboratory of Organic Chemistry, Chemistry Department, University of Thessaloniki, Thessaloniki 540 06, Greece
* Author to whom correspondence should be addressed.
Received: 22 August 2000; in revised form: 5 October 2000 / Accepted: 10 October 2000 / Published: 1 November 2000
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Abstract: Treatment of trimethylsilylethynyl(phenyl)iodonium triflate with the potassium salts of some acidic phenols results in the formation of substitution products (O-trimethylsilylethynylphenols and/or O-ethynylphenols), along with sp2C-H insertion products which afford eventually 2-aroxybenzo[b]furans.
Keywords: Alkynyl iodonium salts; ethynyl phenyl ethers; benzo[b]furans

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MDPI and ACS Style

Nikas, S.; Rodios, N.; Varvoglis, A. The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products. Molecules 2000, 5, 1182-1186.

AMA Style

Nikas S, Rodios N, Varvoglis A. The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products. Molecules. 2000; 5(11):1182-1186.

Chicago/Turabian Style

Nikas, Spyros; Rodios, Nestor; Varvoglis, Anastasios. 2000. "The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products." Molecules 5, no. 11: 1182-1186.

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