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NMR of Polymers. By F. A. Bovey Frank Bovey
Molecules 1998, 3(3), 51-59; doi:10.3390/30300051
Article

Efficient Polymer-Supported Sharpless Alkene Epoxidation Catalyst

1
,
1,*  and 2
Received: 11 January 1998 / Accepted: 13 February 1998 / Published: 17 February 1998
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Abstract

Homogeneous linear poly(tartrate ester) ligands provide high chemical yields and enantiomeric excesses in the epoxidation of trans-hex-2-en-1-ol using Ti(OPri)4-tert-butyl hydroperoxide. Branched poly(tartrate ester) can be use as heterogeneous ligands in the epoxidation of trans-hex-2-en-1-ol using Ti(OPri)4-tert-butyl hydroperoxide. Removal and recovery of the polymer catalyst is a simple filtration at the end of reactions.
Keywords: Asymmetric epoxidation; Sharpless epoxidation; polymer-supported catalyst Asymmetric epoxidation; Sharpless epoxidation; polymer-supported catalyst
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Karjalainen, J.K.; Hormi, O.E.; Sherrington, D.C. Efficient Polymer-Supported Sharpless Alkene Epoxidation Catalyst. Molecules 1998, 3, 51-59.

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