Metal Atom Effect on the Photophysical Properties of Mg(II), Zn(II), Cd(II), and Pd(II) Tetraphenylporphyrin Complexes Proposed as Possible Drugs in Photodynamic Therapy
Abstract
:1. Introduction
2. Results and Discussion
3. Computational Methods
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Compound | Excited State | λtheo (nm) | ΔE (eV) | f | λexp (nm) | Transitions d |
---|---|---|---|---|---|---|
MgTPP | S1 (S’1) | 559 | 2.22 | 0.008 | 607 a | H → L, 54% (H → L + 1, 54%) |
S2 (S’2) | 404 | 3.07 | 1.739 | 428 a | H − 1 → L, 44% (H − 1 → L + 1, 44%) | |
T1 (T’1) | 831 | 1.49 | 0 | 794 c | H → L, 83% (H → L + 1, 83%) | |
T2 (T’2) | 630 | 1.97 | 0 | H − 1→L, 84% (H − 1 → L + 1, 84%) | ||
ZnTPP | S1 (S’1) | 561 | 2.21 | 0.038 | 593 a | H → L, 50% (H → L + 1, 50%) |
S2 (S’2) | 412 | 3.01 | 1.699 | 424 a | H − 1 → L + 1, 47% (H − 1 → L, 47%) | |
T1 (T’1) | 812 | 1.53 | 0 | 778 c | H → L, 70% (H → L + 1, 70%) | |
T2 (T’2) | 626 | 1.98 | 0 | H − 1 → L, 82% (H − 1 → L + 1, 82%) | ||
CdTPP | S1 (S’1) | 549 | 2.26 | 0.013 | 617 a | H → L, 54% (H → L + 1, 54%) |
S2 (S’2) | 397 | 3.12 | 1.670 | 437 a | H − 1 → L+1, 59% (H − 1 → L, 59%) | |
T1 (T’1) | 846 | 1.46 | 0 | 814 c | H → L, 52% (H → L + 1, 52%) | |
T2 (T’2) | 619 | 2.00 | 0 | H − 1 → L, 85% (H – 1 → L + 1, 85%) | ||
PdTPP | S1 (S’1) | 537 | 2.31 | 0.032 | 553 b | H → L, 48% (H → L + 1, 48%) |
S2 (S’2) | 409 | 3.03 | 1.519 | 407 b | H − 1 → L, 59% (H − 1 → L + 1, 59%) | |
T1 (T’1) | 758 | 1.63 | 0 | H → L, 78% (H → L + 1, 78%) | ||
T2 (T’2) | 597 | 2.07 | 0 | H − 1 → L, 84% ( H − 1 → L + 1, 84%) |
MgTPP | ZnTPP | CdTPP | PdTPP | |
---|---|---|---|---|
0.31 0.73 | 1.64 0.68 | 14.01 0.80 | 28.99 0.68 | |
0.15 0.25 | 0.70 0.23 | 9.55 0.26 | 12.81 0.24 | |
0.14 1.58 | 0.38 1.48 | 0.52 1.66 | 4.10 1.40 | |
0.22 1.10 | 0.05 1.03 | 4.52 1.12 | 16.97 0.96 |
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Simone, B.C.D.; Mazzone, G.; Russo, N.; Sicilia, E.; Toscano, M. Metal Atom Effect on the Photophysical Properties of Mg(II), Zn(II), Cd(II), and Pd(II) Tetraphenylporphyrin Complexes Proposed as Possible Drugs in Photodynamic Therapy. Molecules 2017, 22, 1093. https://doi.org/10.3390/molecules22071093
Simone BCD, Mazzone G, Russo N, Sicilia E, Toscano M. Metal Atom Effect on the Photophysical Properties of Mg(II), Zn(II), Cd(II), and Pd(II) Tetraphenylporphyrin Complexes Proposed as Possible Drugs in Photodynamic Therapy. Molecules. 2017; 22(7):1093. https://doi.org/10.3390/molecules22071093
Chicago/Turabian StyleSimone, Bruna Clara De, Gloria Mazzone, Nino Russo, Emilia Sicilia, and Marirosa Toscano. 2017. "Metal Atom Effect on the Photophysical Properties of Mg(II), Zn(II), Cd(II), and Pd(II) Tetraphenylporphyrin Complexes Proposed as Possible Drugs in Photodynamic Therapy" Molecules 22, no. 7: 1093. https://doi.org/10.3390/molecules22071093