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Molecules 2017, 22(12), 2201; doi:10.3390/molecules22122201

Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., Moscow 119991, Russia
Received: 2 November 2017 / Revised: 27 November 2017 / Accepted: 1 December 2017 / Published: 11 December 2017
(This article belongs to the Special Issue Advances in Materials Derived from Polyhedral Boron Clusters)

Abstract

Design of rotatory molecular switches based on extremely stable sandwich organometallic complexes ferrocene and bis(dicarbollide) complexes of transition metals is reviewed. The “on”–“off” switching in these systems can be controlled by various external stimuli such as change of the solution pH, interactions with coordinating species or redox reactions involving the central atom or substituents in the ligands. View Full-Text
Keywords: molecular switches; ferrocene; transition metal bis(dicarbollides) molecular switches; ferrocene; transition metal bis(dicarbollides)
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Sivaev, I.B. Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches. Molecules 2017, 22, 2201.

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