Isolation of a Cyclic (Alkyl)(amino)germylene
AbstractA 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. View Full-Text
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Wang, L.; Lim, Y.S.; Li, Y.; Ganguly, R.; Kinjo, R. Isolation of a Cyclic (Alkyl)(amino)germylene. Molecules 2016, 21, 990.
Wang L, Lim YS, Li Y, Ganguly R, Kinjo R. Isolation of a Cyclic (Alkyl)(amino)germylene. Molecules. 2016; 21(8):990.Chicago/Turabian Style
Wang, Liliang; Lim, Yi S.; Li, Yongxin; Ganguly, Rakesh; Kinjo, Rei. 2016. "Isolation of a Cyclic (Alkyl)(amino)germylene." Molecules 21, no. 8: 990.
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