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Molecules 2016, 21(8), 987; doi:10.3390/molecules21080987

A Well-Defined {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes

1
Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China
2
Engineering Center of Jiangxi University for Lithium Energy, Yichun University, Yichun 336000, China
*
Author to whom correspondence should be addressed.
Academic Editors: Diego A. Alonso and Isidro M. Pastor
Received: 27 May 2016 / Revised: 13 July 2016 / Accepted: 15 July 2016 / Published: 29 July 2016
(This article belongs to the Special Issue Palladium Catalysts 2016)
View Full-Text   |   Download PDF [4888 KB, uploaded 29 July 2016]   |  

Abstract

A palladium (II) complex {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating. View Full-Text
Keywords: palladium (II) complex; Hiyama cross-coupling reaction; unsymmetrical biaryls; synthetic method palladium (II) complex; Hiyama cross-coupling reaction; unsymmetrical biaryls; synthetic method
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Guo, M.; Fu, L.; Li, J.; Zhou, L.; Kang, Y. A Well-Defined {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes. Molecules 2016, 21, 987.

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