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Molecules 2016, 21(5), 636; doi:10.3390/molecules21050636

The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl

1
Department of Chemistry, University of Cyprus, P. O. Box 20537, Nicosia 1678, Cyprus
2
Department of Chemical Research Support, Weizmann Institute of Science, Rehovot 76100, Israel
*
Authors to whom correspondence should be addressed.
Academic Editor: Fawaz Aldabbagh
Received: 18 April 2016 / Revised: 9 May 2016 / Accepted: 10 May 2016 / Published: 14 May 2016
(This article belongs to the Special Issue Free Radicals in Organic Synthesis)
View Full-Text   |   Download PDF [1948 KB, uploaded 14 May 2016]   |  

Abstract

3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (4) crystallizes as chains of radicals where the spin bearing benzotriazinyl moieties are isolated from each other. Magnetic susceptibility studies in the 5–300 K temperature region indicate that radical 4 demonstrates typical paramagnetic behavior stemming from non-interacting S = ½ spins. View Full-Text
Keywords: 1,2,4-benzotriazinyls; hydrazyls; adamantyl; paramagnet; organic radicals; crystal packing 1,2,4-benzotriazinyls; hydrazyls; adamantyl; paramagnet; organic radicals; crystal packing
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Constantinides, C.P.; Berezin, A.A.; Zissimou, G.A.; Manoli, M.; Leitus, G.M.; Koutentis, P.A. The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl. Molecules 2016, 21, 636.

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