The Role of Concentration and Solvent Character in the Molecular Organization of Humic Acids
AbstractThe molecular organization of humic acids in different aqueous solutions was studied over a wide concentration range (0.01–10 g·dm−3). Solutions of humic acids were prepared in three different media: NaOH, NaCl, and NaOH neutralized by HCl after dissolution of the humic sample. Potentiometry, conductometry, densitometry, and high resolution ultrasound spectrometry were used in order to investigate conformational changes in the humic systems. The molecular organization of humic acids in the studied systems could be divided into three concentration ranges. The rearrangements were observed at concentrations of ~0.02 g·dm−3 and ~1 g·dm−3. The first “switch-over point” was connected with changes in the hydration shells of humic particles resulting in changes in their elasticity. The compressibility of water in the hydration shells is less than the compressibility of bulk water. The transfer of hydration water into bulk water increased the total compressibility of the solution, reducing the ultrasonic velocity. The aggregation of humic particles and the formation of rigid structures in systems with concentrations higher than 1 g·dm−3 was detected. View Full-Text
Scifeed alert for new publicationsNever miss any articles matching your research from any publisher
- Get alerts for new papers matching your research
- Find out the new papers from selected authors
- Updated daily for 49'000+ journals and 6000+ publishers
- Define your Scifeed now
Klučáková, M.; Věžníková, K. The Role of Concentration and Solvent Character in the Molecular Organization of Humic Acids. Molecules 2016, 21, 1410.
Klučáková M, Věžníková K. The Role of Concentration and Solvent Character in the Molecular Organization of Humic Acids. Molecules. 2016; 21(11):1410.Chicago/Turabian Style
Klučáková, Martina; Věžníková, Kateřina. 2016. "The Role of Concentration and Solvent Character in the Molecular Organization of Humic Acids." Molecules 21, no. 11: 1410.
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.