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Molecules 2015, 20(9), 16103-16126; doi:10.3390/molecules200916103

Enantioselective Cycloaddition Reactions Catalyzed by BINOL-Derived Phosphoric Acids and N-Triflyl Phosphoramides: Recent Advances

Department of Chemistry and Pharmacy, Organic Chemistry Chair I and Interdisciplinary Center for Molecular Materials, University of Erlangen-Nürnberg, Henkestrasse 42, Erlangen 91054, Germany
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Academic Editor: Raquel P. Herrera
Received: 20 July 2015 / Revised: 22 August 2015 / Accepted: 28 August 2015 / Published: 3 September 2015
(This article belongs to the Collection Recent Advances in Organocatalysis)

Abstract

Over the last several years there has been a huge increase in the development and applications of new efficient organocatalysts for enantioselective pericyclic reactions, which represent one of the most powerful types of organic transformations. Among these processes are cycloaddition reactions (e.g., [3+2]; formal [3+3]; [4+2]; vinylogous [4+2] and 1,3-dipolar cycloadditions), which belong to the most utilized reactions in organic synthesis of complex nitrogen- and oxygen-containing heterocyclic molecules. This review presents the breakthrough realized in this field using chiral BINOL-derived phosphoric acids and N-triflyl phosphoramide organocatalysts. View Full-Text
Keywords: cycloaddition reactions; BINOL-derived phosphoric acids; N-triflyl phosphoramides; enantioselective pericyclic reactions cycloaddition reactions; BINOL-derived phosphoric acids; N-triflyl phosphoramides; enantioselective pericyclic reactions
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Held, F.E.; Grau, D.; Tsogoeva, S.B. Enantioselective Cycloaddition Reactions Catalyzed by BINOL-Derived Phosphoric Acids and N-Triflyl Phosphoramides: Recent Advances. Molecules 2015, 20, 16103-16126.

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