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Molecules 2015, 20(8), 15023-15032; doi:10.3390/molecules200815023

Copper-Catalyzed Dimerization/Cyclization of Itaconates

College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
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Author to whom correspondence should be addressed.
Academic Editor: Derek J. McPhee
Received: 7 June 2015 / Revised: 3 August 2015 / Accepted: 5 August 2015 / Published: 17 August 2015
(This article belongs to the Section Organic Synthesis)
View Full-Text   |   Download PDF [717 KB, uploaded 17 August 2015]   |  

Abstract

A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields. View Full-Text
Keywords: copper; catalysis; domino reaction; itaconate; dimerization; cyclopentanone copper; catalysis; domino reaction; itaconate; dimerization; cyclopentanone
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Li, Z.; Li, R.; Jiang, L.; Li, Z. Copper-Catalyzed Dimerization/Cyclization of Itaconates. Molecules 2015, 20, 15023-15032.

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