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Molecules 2015, 20(8), 13794-13813; doi:10.3390/molecules200813794

Synthesis of Chiral 1,4,2-Oxazaphosphepines

Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62209 Cuernavaca, Morelos, Mexico
These authors contributed equally to this work.
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Academic Editor: Jean Jacques Vanden Eynde
Received: 11 June 2015 / Revised: 17 July 2015 / Accepted: 22 July 2015 / Published: 29 July 2015
(This article belongs to the Section Organic Synthesis)
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Abstract

Synthesis and structural characterization of 1,4,2-oxazaphosphepines is described. The 1,4,2-oxazaphosphepines were obtained from reaction of chiral 1,3-benzoxazines with dichlorophenylphosphine or triethyl phosphite. The configuration of some of these compounds was stablished by X-ray analysis. View Full-Text
Keywords: 1,4,2-oxazaphosphepines; 1,3-benzoxazines; chiral o-hydroxybenzylamines; aminophenols 1,4,2-oxazaphosphepines; 1,3-benzoxazines; chiral o-hydroxybenzylamines; aminophenols
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Salgado-Escobar, O.; Chavelas-Hernández, L.; Domínguez-Mendoza, B.E.; Linzaga-Elizalde, I.; Ordoñez, M. Synthesis of Chiral 1,4,2-Oxazaphosphepines. Molecules 2015, 20, 13794-13813.

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