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Molecules 2015, 20(4), 6409-6418; doi:10.3390/molecules20046409

Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents

1
Departamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain
2
Instituto Universitario de Bio-Orgánica "Antonio González" (IUBO-AG), Universidad de La Laguna, Astrofísico Francisco Sánchez 2, 38206 La Laguna, Spain
3
Servicio de Difracción de Rayos X, Plataforma Nucleus, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain
*
Author to whom correspondence should be addressed.
Academic Editor: Raquel P. Herrera
Received: 12 March 2015 / Revised: 2 April 2015 / Accepted: 3 April 2015 / Published: 10 April 2015
(This article belongs to the Collection Recent Advances in Organocatalysis)
View Full-Text   |   Download PDF [955 KB, uploaded 20 April 2015]   |  

Abstract

The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives. View Full-Text
Keywords: organocatalysis; Nazarov reagents; sulfones; decalins organocatalysis; Nazarov reagents; sulfones; decalins
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Peña, J.; Silveira-Dorta, G.; Moro, R.F.; Garrido, N.M.; Marcos, I.S.; Sanz, F.; Díez, D. Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents. Molecules 2015, 20, 6409-6418.

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