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Molecules 2015, 20(12), 22635-22644; doi:10.3390/molecules201219874

Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes

Centre in Green Chemistry and Catalysis, Department of Chemistry, University of Sherbrooke, 2500 boul. de l’Université, Sherbrooke, QC J1K 2R1, Canada
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Author to whom correspondence should be addressed.
Academic Editors: Wesley Moran and Arantxa Rodríguez
Received: 25 November 2015 / Revised: 10 December 2015 / Accepted: 15 December 2015 / Published: 17 December 2015
(This article belongs to the Special Issue Hypervalent Iodine Chemistry)
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Abstract

The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed. View Full-Text
Keywords: hypervalent iodine; (diacetoxyiodo)arenes; metathesis hypervalent iodine; (diacetoxyiodo)arenes; metathesis
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Jobin-Des Lauriers, A.; Legault, C.Y. Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes. Molecules 2015, 20, 22635-22644.

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