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Molecules 2015, 20(1), 1262-1276; doi:10.3390/molecules20011262

TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion

1
Procédés, Université 8 mai 1945 Guelma, BP 401, Guelma 24000, Algeria
2
Laboratoire de Synthèse et de Biocatalyse Organique (LSBO), Faculté des Sciences, Université Badji Mokhtar-Annaba, BP 12 El-Hadjar, Annaba 23000, Algeria
3
Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France
*
Author to whom correspondence should be addressed.
Academic Editor: Derek J. McPhee
Received: 11 December 2014 / Accepted: 8 January 2015 / Published: 14 January 2015
(This article belongs to the Section Organic Synthesis)
View Full-Text   |   Download PDF [753 KB, uploaded 14 January 2015]   |  

Abstract

We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy. View Full-Text
Keywords: TDAE; benzoxazolone; benzoxazolinonic anion; benzylic alcohols; oxiranes TDAE; benzoxazolone; benzoxazolinonic anion; benzylic alcohols; oxiranes
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Nadji-Boukrouche, A.R.; Khoumeri, O.; Terme, T.; Liacha, M.; Vanelle, P. TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion. Molecules 2015, 20, 1262-1276.

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