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Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity
AbstractThe complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4)·EtOH·H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied.
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Kopel, P.; Dolezal, K.; Langer, V.; Jun, D.; Adam, V.; Kuca, K.; Kizek, R. Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity. Molecules 2014, 19, 4338-4354.View more citation formats
Kopel P, Dolezal K, Langer V, Jun D, Adam V, Kuca K, Kizek R. Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity. Molecules. 2014; 19(4):4338-4354.Chicago/Turabian Style
Kopel, Pavel; Dolezal, Karel; Langer, Vratislav; Jun, Daniel; Adam, Vojtech; Kuca, Kamil; Kizek, Rene. 2014. "Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity." Molecules 19, no. 4: 4338-4354.
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