Click Reactions as a Key Step for an Efficient and Selective Synthesis of D-Xylose-Based ILs

doi:10.3390/molecules180911512

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Molecules 2013, 18(9), 11512-11525; doi:10.3390/molecules180911512

Article

Click Reactions as a Key Step for an Efficient and Selective Synthesis of D-Xylose-Based ILs

Nadège Ferlin¹, Sylvain Gatard¹, Albert Nguyen Van Nhien², Matthieu Courty³ and Sandrine Bouquillon^1,*

¹ Institut de Chimie Moléculaire de Reims, UMR CNRS 6229, Université de Reims Champagne-Ardenne, Boîte 44, B.P. 1039, Reims F-51687, France ² Laboratoire des Glucides FRE 3517, Université de Picardie Jules Verne, UFR des Sciences, 33 rue Saint Leu, Amiens Cedex 1 80039, France ³ Laboratoire de Réactivité et de Chimie des Solides UMR CNRS 7314, Université de Picardie Jules Verne, UFR des Sciences, 33 rue Saint Leu, Amiens Cedex 1 80039, France

* Author to whom correspondence should be addressed.

Received: 27 June 2013; in revised form: 7 August 2013 / Accepted: 10 September 2013 / Published: 17 September 2013

(This article belongs to the Special Issue Advances in Click Chemistry)

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Abstract: D-Xylose-based ionic liquids have been prepared from D-xylose following a five steps reaction sequence, the key step being a click cycloaddition. These ionic liquids (ILs) have been characterized through classical analytical methods (IR, NMR, mass spectroscopy, elemental analysis) and their stability constants, Tg and Tdec, were also determined. Considering their properties and their hydrophilicity, these compounds could be alternative solvents for chemical applications under mild conditions.

Keywords: _{ionic liquids; D-xylose; click chemistry}

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MDPI and ACS Style

Ferlin, N.; Gatard, S.; Van Nhien, A.N.; Courty, M.; Bouquillon, S. Click Reactions as a Key Step for an Efficient and Selective Synthesis of D-Xylose-Based ILs. Molecules 2013, 18, 11512-11525.

AMA Style

Ferlin N, Gatard S, Van Nhien AN, Courty M, Bouquillon S. Click Reactions as a Key Step for an Efficient and Selective Synthesis of D-Xylose-Based ILs. Molecules. 2013; 18(9):11512-11525.

Chicago/Turabian Style

Ferlin, Nadège; Gatard, Sylvain; Van Nhien, Albert N.; Courty, Matthieu; Bouquillon, Sandrine. 2013. "Click Reactions as a Key Step for an Efficient and Selective Synthesis of D-Xylose-Based ILs." Molecules 18, no. 9: 11512-11525.

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