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Molecules 2013, 18(9), 11429-11451; doi:10.3390/molecules180911429
Article

Harvestman Phenols and Benzoquinones: Characterisation and Biosynthetic Pathway

1, 1, 1, 2, 3 and 1,*
Received: 19 July 2013; in revised form: 5 September 2013 / Accepted: 6 September 2013 / Published: 16 September 2013
(This article belongs to the Section Metabolites)
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Abstract: Benzoquinones are usually present in arthropod defence exudates. Here, we describe the chemical profiles of 12 harvestman species belonging to the neotropical family Gonyleptidae. Nine of the studied species produced benzoquinones, while three produced alkyl phenols. Two benzoquinones and one phenol exhibited biological activity against bacteria and fungi. We also studied the biosynthesis of 2-ethyl-1,4-benzoquinone by feeding Magnispina neptunus individuals with 13C-labelled precursors; the benzoquinones were biosynthesised through a polyketide pathway using acetate and propionate building blocks.
Keywords: chemical defence; NMR spectroscopy; arthropod biosynthesis; labelled precursors; evolution; chemotaxonomy; Opiliones chemical defence; NMR spectroscopy; arthropod biosynthesis; labelled precursors; evolution; chemotaxonomy; Opiliones
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Rocha, D.F.O.; Wouters, F.C.; Zampieri, D.S.; Brocksom, T.J.; Machado, G.; Marsaioli, A.J. Harvestman Phenols and Benzoquinones: Characterisation and Biosynthetic Pathway. Molecules 2013, 18, 11429-11451.

AMA Style

Rocha DFO, Wouters FC, Zampieri DS, Brocksom TJ, Machado G, Marsaioli AJ. Harvestman Phenols and Benzoquinones: Characterisation and Biosynthetic Pathway. Molecules. 2013; 18(9):11429-11451.

Chicago/Turabian Style

Rocha, Daniele F.O.; Wouters, Felipe C.; Zampieri, Dávila S.; Brocksom, Timothy J.; Machado, Glauco; Marsaioli, Anita J. 2013. "Harvestman Phenols and Benzoquinones: Characterisation and Biosynthetic Pathway." Molecules 18, no. 9: 11429-11451.



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