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Molecules 2013, 18(8), 9650-9662; doi:10.3390/molecules18089650

Ring Expansion of Vinylaziridines through the Strain-Release Pericyclic Reaction: Recent Developments and Applications

College of Pharmacy and Research Institute of Pharmaceutical Sciences, Gyeongsang National University, Jinju daero, Jinju, Gyeongnam 660-751, Korea
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Received: 23 July 2013 / Revised: 1 August 2013 / Accepted: 7 August 2013 / Published: 12 August 2013
(This article belongs to the Special Issue Bioorthogonal Chemistry)

Abstract

Recent syntheses of azetidines, pyrrolidines, piperidines and azepines through cycloaddition or sigmatropic rearrangements of vinylaziridines are described. Applications to natural product synthesis and mechanistic investigations are also summarized. View Full-Text
Keywords: vinylaziridines; cycloaddition; rearrangement; ring expansion vinylaziridines; cycloaddition; rearrangement; ring expansion
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Heo, Y.M.; Paek, S.-M. Ring Expansion of Vinylaziridines through the Strain-Release Pericyclic Reaction: Recent Developments and Applications. Molecules 2013, 18, 9650-9662.

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