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Molecules 2013, 18(12), 15207-15219; doi:10.3390/molecules181215207
Article

Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid

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Received: 16 October 2013 / Revised: 22 November 2013 / Accepted: 27 November 2013 / Published: 10 December 2013
(This article belongs to the Special Issue Palladium Catalysts)
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Abstract

A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain lengths. X-ray crystallography was employed to obtain the structure of the o,p-oligophenylene 9-mer.
Keywords: palladium; Suzuki-Miyaura coupling; oligoarene; nonaflate palladium; Suzuki-Miyaura coupling; oligoarene; nonaflate
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Yamaguchi, M.; Kimura, T.; Shinohara, N.; Manabe, K. Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid. Molecules 2013, 18, 15207-15219.

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