Next Article in Journal
Enhancement of Gene Silencing Effect and Membrane Permeability by Peptide-Conjugated 27-Nucleotide Small Interfering RNA
Previous Article in Journal
Primary Investigation of the Preparation of Nanoparticles by Precipitation
Previous Article in Special Issue
A New Facile Synthesis of D4-Pterosin B and D4-Bromopterosin, Deuterated Analogues of Ptaquiloside
Molecules 2012, 17(9), 11079-11088; doi:10.3390/molecules170911079
Article

Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis

* , ,  and *
Received: 29 June 2012 / Revised: 8 August 2012 / Accepted: 3 September 2012 / Published: 13 September 2012
(This article belongs to the Special Issue Challenges in Synthetic Chemistry)
Download PDF [353 KB, uploaded 18 June 2014]

Abstract

One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
Keywords: samarium diiodide; electrolysis; cyclization; hydrindanone samarium diiodide; electrolysis; cyclization; hydrindanone
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote
MDPI and ACS Style

Sono, M.; Ise, N.; Shoji, T.; Tori, M. Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis. Molecules 2012, 17, 11079-11088.

View more citation formats

Related Articles

Article Metrics

Comments

Citing Articles

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert