Molecules 2012, 17(9), 11079-11088; doi:10.3390/molecules170911079
Article

Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis

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Received: 29 June 2012; in revised form: 8 August 2012 / Accepted: 3 September 2012 / Published: 13 September 2012
(This article belongs to the Special Issue Challenges in Synthetic Chemistry)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
Keywords: samarium diiodide; electrolysis; cyclization; hydrindanone
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MDPI and ACS Style

Sono, M.; Ise, N.; Shoji, T.; Tori, M. Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis. Molecules 2012, 17, 11079-11088.

AMA Style

Sono M, Ise N, Shoji T, Tori M. Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis. Molecules. 2012; 17(9):11079-11088.

Chicago/Turabian Style

Sono, Masakazu; Ise, Natsuko; Shoji, Tsutomu; Tori, Motoo. 2012. "Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis." Molecules 17, no. 9: 11079-11088.

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