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Molecules 2012, 17(9), 11079-11088; doi:10.3390/molecules170911079
Article

Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis

* , ,  and *
Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan
* Authors to whom correspondence should be addressed.
Received: 29 June 2012 / Revised: 8 August 2012 / Accepted: 3 September 2012 / Published: 13 September 2012
(This article belongs to the Special Issue Challenges in Synthetic Chemistry)
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Abstract

One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
Keywords: samarium diiodide; electrolysis; cyclization; hydrindanone samarium diiodide; electrolysis; cyclization; hydrindanone
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Sono, M.; Ise, N.; Shoji, T.; Tori, M. Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis. Molecules 2012, 17, 11079-11088.

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