Next Article in Journal
Enhancement of Gene Silencing Effect and Membrane Permeability by Peptide-Conjugated 27-Nucleotide Small Interfering RNA
Previous Article in Journal
Primary Investigation of the Preparation of Nanoparticles by Precipitation
Previous Article in Special Issue
A New Facile Synthesis of D4-Pterosin B and D4-Bromopterosin, Deuterated Analogues of Ptaquiloside
Article Menu

Article Versions

Export Article

Open AccessArticle
Molecules 2012, 17(9), 11079-11088; doi:10.3390/molecules170911079

Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis

Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan
*
Authors to whom correspondence should be addressed.
Received: 29 June 2012 / Revised: 8 August 2012 / Accepted: 3 September 2012 / Published: 13 September 2012
(This article belongs to the Special Issue Challenges in Synthetic Chemistry)
Download PDF [353 KB, uploaded 18 June 2014]

Abstract

One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
Keywords: samarium diiodide; electrolysis; cyclization; hydrindanone samarium diiodide; electrolysis; cyclization; hydrindanone
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Sono, M.; Ise, N.; Shoji, T.; Tori, M. Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis. Molecules 2012, 17, 11079-11088.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top