Molecules 2012, 17(12), 14700-14732; doi:10.3390/molecules171214700

New Advances in Titanium-Mediated Free Radical Reactions

1 Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, P.zza Leonardo da Vinci 32, 20133 Milano, Italy 2 INSTM (National Consortium for Materials Science and Technology) Local Unit, Politecnico di Milano, 20133 Milan, Italy
* Author to whom correspondence should be addressed.
Received: 31 October 2012; in revised form: 28 November 2012 / Accepted: 6 December 2012 / Published: 11 December 2012
(This article belongs to the Special Issue Transition Metals Catalysis)
PDF Full-text Download PDF Full-Text [781 KB, Updated Version, uploaded 20 December 2012 08:57 CET]
The original version is still available [781 KB, uploaded 11 December 2012 09:10 CET]
Abstract: Titanium complexes have been widely used as catalysts for C‑C bond-forming processes via free-radical routes. Herein we provide an overview of some of the most significant contributions in the field, that covers the last decade, emphasizing the key role played by titanium salts in the promotion of selective reactions aimed at the synthesis of multifunctional organic compounds, including nucleophilic radical additions to imines, pinacol and coupling reactions, ring opening of epoxides and living polymerization.
Keywords: radical chemistry; titanium; titanocene; TiCl3; TiCl4; nucleophilic addition; pinacolization; cross-coupling; ring opening of epoxides; multicomponent reactions

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Rossi, B.; Prosperini, S.; Pastori, N.; Clerici, A.; Punta, C. New Advances in Titanium-Mediated Free Radical Reactions. Molecules 2012, 17, 14700-14732.

AMA Style

Rossi B, Prosperini S, Pastori N, Clerici A, Punta C. New Advances in Titanium-Mediated Free Radical Reactions. Molecules. 2012; 17(12):14700-14732.

Chicago/Turabian Style

Rossi, Bianca; Prosperini, Simona; Pastori, Nadia; Clerici, Angelo; Punta, Carlo. 2012. "New Advances in Titanium-Mediated Free Radical Reactions." Molecules 17, no. 12: 14700-14732.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert