Molecules 2012, 17(11), 13157-13174; doi:10.3390/molecules171113157
Article

Effect of Surfactants and Manufacturing Methods on the Electrical and Thermal Conductivity of Carbon Nanotube/Silicone Composites

1 Polymer Centre, Faculty of Technology, Tomas Bata University in Zlín, Zlín 760 01, Czech Republic 2 Centre of Polymer Systems, University Institute, Tomas Bata University in Zlín, Nad Ovcirnou, Zlín 760 01, Czech Republic 3 Polymer Institute, Slovak Academy of Sciences, Bratislava 845 41, Slovakia
* Author to whom correspondence should be addressed.
Received: 24 September 2012; in revised form: 25 October 2012 / Accepted: 29 October 2012 / Published: 5 November 2012
PDF Full-text Download PDF Full-Text [2419 KB, Updated Version, uploaded 6 November 2012 17:13 CET]
The original version is still available [2420 KB, uploaded 5 November 2012 13:48 CET]
Abstract: The effect of ionic surfactants and manufacturing methods on the separation and distribution of multi-wall carbon nanotubes (CNTs) in a silicone matrix are investigated. The CNTs are dispersed in an aqueous solution of the anionic surfactant dodecylbenzene sulfonic acid (DBSA), the cationic surfactant cetyltrimethylammonium bromide (CTAB), and in a DBSA/CTAB surfactant mixture. Four types of CNT-based composites of various concentrations from 0 to 6 vol.% are prepared by simple mechanical mixing and sonication. The morphology, electrical and thermal conductivity of the CNT-based composites are analyzed. The incorporation of both neat and modified CNTs leads to an increase in electrical and thermal conductivity. The dependence of DC conductivity versus CNT concentration shows percolation behaviour with a percolation threshold of about 2 vol.% in composites with neat CNT. The modification of CNTs by DBSA increases the percolation threshold to 4 vol.% due to the isolation/separation of individual CNTs. This, in turn, results in a significant decrease in the complex permittivity of CNT–DBSA-based composites. In contrast to the percolation behaviour of DC conductivity, the concentration dependence of thermal conductivity exhibits a linear dependence, the thermal conductivity of composites with modified CNTs being lower than that of composites with neat CNTs. All these results provide evidence that the modification of CNTs by DBSA followed by sonication allows one to produce composites with high homogeneity.
Keywords: multi-wall carbon nanotubes; modification of carbon nanotubes by ionic surfactants; silicone based composites; electrical conductivity; thermal conductivity; percolation threshold; complex permittivity

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Vilčáková, J.; Moučka, R.; Svoboda, P.; Ilčíková, M.; Kazantseva, N.; Hřibová, M.; Mičušík, M.; Omastová, M. Effect of Surfactants and Manufacturing Methods on the Electrical and Thermal Conductivity of Carbon Nanotube/Silicone Composites. Molecules 2012, 17, 13157-13174.

AMA Style

Vilčáková J, Moučka R, Svoboda P, Ilčíková M, Kazantseva N, Hřibová M, Mičušík M, Omastová M. Effect of Surfactants and Manufacturing Methods on the Electrical and Thermal Conductivity of Carbon Nanotube/Silicone Composites. Molecules. 2012; 17(11):13157-13174.

Chicago/Turabian Style

Vilčáková, Jarmila; Moučka, Robert; Svoboda, Petr; Ilčíková, Markéta; Kazantseva, Natalia; Hřibová, Martina; Mičušík, Matej; Omastová, Mária. 2012. "Effect of Surfactants and Manufacturing Methods on the Electrical and Thermal Conductivity of Carbon Nanotube/Silicone Composites." Molecules 17, no. 11: 13157-13174.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert