Bismuth Modified Carbon-Based Electrodes for the Determination of Selected Neonicotinoid Insecticides
Abstract
:1. Introduction
2. Results and Discussion
2.1. Bismuth-Film Modified Glassy Carbon Electrode for the Determination of Clothianidin
2.2. Bulk Modified Tricresyl Phosphate-Based Carbon Paste Electrode in the Imidacloprid Analysis
3. Experimental
3.1. Chemicals and Solutions
3.2. Apparatus
3.3. Procedures
3.3.1. Bismuth-Film Deposition
3.3.2. Voltammetry
3.3.3. Scanning Electron Microscopy
4. Conclusions
Acknowledgements
References
- Wang, J.; Lu, J.; Hočevar, S.B.; Farias, P.A.M.; Ogorevc, B. Bismuth-coated carbon electrodes for anodic stripping voltammetry. Anal. Chem. 2000, 72, 3218–3222. [Google Scholar]
- Wang, J. Stripping analysis at bismuth electrodes: A review. Electroanalysis 2005, 17, 1341–1346. [Google Scholar] [CrossRef]
- Švancara, I.; Vytřas, K. Electroanalysis with bismuth electrodes: State of the art and future prospects. Chem. Listy 2006, 100, 90–113. [Google Scholar]
- Guzsvány, V. Bismuth-Film Electrode for Voltammetric Analysis. J. Flow Injection Anal. 2007, 24, 126. [Google Scholar]
- Kokkinos, C.; Economou, A. Stripping analysis at bismuth-based electrodes. Curr. Anal. Chem. 2008, 4, 183–190. [Google Scholar]
- Švancara, I.; Prior, C.; Hočevar, S.B.; Wang, J. A decade with bismuth-based electrodes in electroanalysis. Electroanalysis 2010, 22, 1405–1420. [Google Scholar] [CrossRef]
- Guzsvány, V.; Kádár, M.; Gaál, F.; Bjelica, L.; Tóth, K. Bismuth film electrode for the cathodic electrochemical determination of thiamethoxam. Electroanalysis 2006, 18, 1363–1371. [Google Scholar] [CrossRef]
- Gaál, F.F.; Guzsvány, V.J.; Bjelica, L.J. Determination of various insecticides and pharmaceuticals using differently modified glassy carbon electrodes. J. Serb. Chem. Soc. 2007, 72, 1465–1475. [Google Scholar] [CrossRef]
- Guzsvány, V.; Kádár, M.; Papp, Z.; Bjelica, L.; Gaál, F.; Tóth, K. Monitoring of photocatalytic degradation of selected neonicotinoid insecticides by cathodic voltammetry with a bismuth film electrode. Electroanalysis 2008, 20, 291–300. [Google Scholar] [CrossRef]
- Du, D.; Ye, X.; Zhang, J.; Liu, D. Cathodic electrochemical analysis of methyl parathion at bismuth-film-modified glassy carbon electrode. Electrochim. Acta 2008, 53, 4478–4484. [Google Scholar] [CrossRef]
- Moreno, M.; Bermejo, E.; Chicharro, M.; Zapardiel, A.; Arribas, A.S. Cathodic electrochemical determination of herbicides in acid media using a bismuth film electrode. Electroanalysis 2009, 21, 415–421. [Google Scholar]
- de Figueiredo-Filho, L.C.S.; dos Santos, V.B.; Janegitz, B.C.; Guerreiro, T.B.; Fatibello-Filho, O.; Faria, R.C.; Marcolino-Junior, L.H. Differential Pulse Voltammetric Determination of Paraquat Using a Bismuth-Film Electrode. Electroanalysis 2010, 22, 1260–1266. [Google Scholar] [CrossRef]
- Claux, B.; Vittori, O. Bismuth film electrode as an alternative for mercury electrodes: Determination of azo dyes and application for detection in food stuffs. Electroanalysis 2007, 19, 2243–2246. [Google Scholar] [CrossRef]
- Nigović, B.; Šimunić, B.; Hočevar, S. Voltammetric measurements of aminosalicylate drugs using bismuth film electrode. Electrochim. Acta 2009, 54, 5678–5683. [Google Scholar] [CrossRef]
- Campestrini, I.; De Braga, O.C.; Vieira, I.C.; Spinelli, A. Application of bismuth-film electrode for cathodic electroanalytical determination of sulfadiazine. Electrochim. Acta 2010, 55, 4970–4975. [Google Scholar] [CrossRef]
- Hočevar, S.; Švancara, I.; Vytřas, K.; Ogorevc, B. Novel electrode for electrochemical stripping analysis based on carbon paste modified with bismuth powder. Electrochim. Acta 2005, 51, 706–710. [Google Scholar] [CrossRef]
- Baldrianová, L.; Agrafiotou, P.; Švancara, I.; Vytřas, K.; Sotiropoulos, S. The determination of cysteine at Bi-powder carbon paste electrodes by cathodic stripping voltammetry. Electrochem. Commun. 2008, 10, 918–921. [Google Scholar]
- Jeschke, P.; Nauen, R.; Schindler, M.; Elbert, A. Overview of the Status and Global Strategy for Neonicotinoids. J. Agric. Food Chem. 2011, 59, 2897–2908. [Google Scholar] [CrossRef]
- Jeschke, P.; Nauen, R. Neonicotinoids - From zero to hero in insecticide chemistry. Pest Manag. Sci. 2008, 64, 1084–1098. [Google Scholar] [CrossRef]
- Elbert, A.; Haas, M.; Springer, B.; Thielert, W.; Nauen, R. Applied aspects of neonicotinoid uses in crop protection. Pest Manag. Sci. 2008, 64, 1099–1105. [Google Scholar] [CrossRef]
- Obana, H.; Okihashi, M.; Akutsu, K.; Kitagawa, Y.; Hori, S. Determination of acetamiprid, imidacloprid, and nitenpyram residues in vegetables and fruits by high-performance liquid chromatography with diode-array detection. J. Agric. Food Chem. 2002, 50, 4464–4467. [Google Scholar]
- Mandić, A.; Lazić, S.; Ökrész, S.N.; Gaál, F. Determination of the insecticide Imidacloprid in potato (Solanum tuberosum L.) and onion (Allium cepa) by high-performance liquid chromatography with diode-array detection. J. Anal. Chem. 2005, 12, 1134–1138. [Google Scholar]
- Seccia, S.; Fidente, P.; Montesano, D.; Morrica, P. Determination of neonicotinoid insecticides residues in bovine milk samples by solid-phase extraction clean-up and liquid chromatography with diode-array detection. J. Chromatogr. A 2008, 1214, 115–120. [Google Scholar] [CrossRef]
- Obana, H.; Okihashi, M.; Akutsu, K.; Kitagawa, Y.; Hori, S. Determination of neonicotinoid pesticide residues in vegetables and fruits with solid phase extraction and liquid chromatography mass spectrometry. J. Agric. Food Chem. 2003, 51, 2501–2505. [Google Scholar] [CrossRef]
- Seccia, S.; Fidente, P.; Barbini, D.A.; Moricca, P. Multiresidue determination of nicotinoid insecticide residues in drinking water by liquid chromatography with electrospray ionization mass spectrometry. Anal. Chim. Acta 2005, 553, 21–26. [Google Scholar] [CrossRef]
- Guzsvány, V.; Madžgalj, A.; Trebše, P.; Gaál, F.; Franko, M. Determination of selected neonicotinoid insecticides by liquid chromatography with thermal lens spectrometric detection. Environ. Chem. Lett. 2007, 5, 203–208. [Google Scholar] [CrossRef]
- de Erenchun, N.R.; de Balugera, Z.G.; Goicolea, M.A.; Barrio, R.J. Determination of imidacloprid and its major metabolite in soils by liquid chromatography with pulsed reductive amperometric detection. Anal. Chim. Acta 1997, 349, 199–206. [Google Scholar] [CrossRef]
- Guzsvány, V.; Gaál, F.; Bjelica, L. Voltammetric determination of imidacloprid and thiamethoxam. J. Serb. Chem. Soc. 2005, 70, 735–743. [Google Scholar] [CrossRef]
- Guzsvány, V.; Kádár, M.; Gaál, F.; Tóth, K.; Bjelica, L. Rapid differential pulse polarographic determination of thiamethoxam in commercial formulations and some real samples. Microchim. Acta 2006, 154, 321–328. [Google Scholar] [CrossRef]
- Papp, Z.; Švancara, I.; Guzsvány, V.; Vytřas, K.; Gaál, F. Voltammetric Determination of Imidacloprid Insecticide in Selected Samples Using a Carbon Paste Electrode. Microchim. Acta 2009, 166, 169–175. [Google Scholar] [CrossRef]
- Papp, Z.; Guzsvány, V.; Kubiak, S.; Bobrowski, A.; Bjelica, L. Voltammetric Determination of the Neonicotinoid Insecticide Thiamethoxam Using a Tricresyl Phosphate-Based Carbon Paste Electrode. J. Serb. Chem. Soc. 2010, 75, 681–687. [Google Scholar] [CrossRef]
- Papp, Z.; Guzsvány, V.; Švancara, I.; Vytřas, K. Carbon Paste Electrodes for the Analysis of Some Agricultural Pollutants and Trace Metals. J. Agric. Sci. Technol. 2011, 5, 85–92. [Google Scholar]
- Guziejewski, D.; Skrzypek, S.; Łuczak, A.; Ciesielski, W. Cathodic stripping voltammetry of clothianidin: Application to environmental studies. Collect. Czech. Chem. Commun. 2011, 76, 131–142. [Google Scholar] [CrossRef]
- Navalón, A.; Ei-Khattabi, R.; González-Casado, A.; Vilchez, J.L. Differential-pulse polarographic determination of the insecticide imidacloprid in commercial formulations. Mikrochim. Acta 1999, 130, 261–265. [Google Scholar] [CrossRef]
- Guiberteau, A.; Galeano, T.; Mora, N.; Parrilla, P.; Salinas, F. Study and determination of the pesticide imidacloprid by square wave adsorptive stripping voltammetry. Talanta 2001, 53, 943–949. [Google Scholar] [CrossRef]
- vancara, I.; Baldrianová, L.; Vlček, M.; Metelka, R.; Vytřas, K. A role of the plating regime in the deposition of bismuth films onto a carbon paste electrode. Microscopic study. Electroanalysis 2005, 17, 120–126. [Google Scholar] [CrossRef]
- Tesařová, E.; Heras, A.; Colina, Á.; Ruiz, V.; Švancara, I.; Vytřas, K.; López-Palacios, J. A spectroelectrochemical approach to the electrodeposition of bismuth film electrodes and their use in stripping analysis. Anal. Chim. Acta 2008, 608, 140–146. [Google Scholar] [CrossRef]
- Królicka, A.; Bobrowski, A. Bismuth film electrode for adsorptive stripping voltammetry - Electrochemical and microscopic study. Electrochem. Commun. 2004, 6, 99–104. [Google Scholar] [CrossRef]
- Królicka, A.; Bobrowski, A.; Kowal, A. Effects of Electroplating Variables on the Voltammetric Properties of Bismuth Deposits Plated Potentiostatically. Electroanalysis 2006, 18, 1649–1657. [Google Scholar]
- Nunes, L.M.S.; Faria, R.C. The influence of the electrodeposition conditions on the electroanalytical performance of the bismuth film electrode for lead determination. Electroanalysis 2008, 20, 2259–2263. [Google Scholar] [CrossRef]
- Grinciene, G.; Selskiene, A.; Verbickas, R.; Norkus, E.; Pauliukaite, R. Peculiarities of electrochemical bismuth film formation in the presence of bromide and heavy metal ions. Electroanalysis 2009, 21, 1743–1749. [Google Scholar] [CrossRef]
- Bobrowski, A.; Królicka, A.; Zarebski, J. Morphology and electrochemical properties of the bismuth film electrode ex situ electrochemically plated from perchloric acid. Electroanalysis 2010, 22, 1421–1427. [Google Scholar] [CrossRef]
- Dejmková, H.; Zima, J.; Barek, J. Application of Carbon Paste Electrodes with Admixed Bismuth Powder for the Determination of 4-Amino-3-nitrophenol. In Sensing in Electroanalysis; Vytřas, K., Švancara, I., Kalcher, K., Eds.; University of Pardubice: Pardubice, Czech Republic, 2008; Volume 3, pp. 83–89. [Google Scholar]
- Sample Availability: Samples of the compounds are not available from the authors.
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Guzsvány, V.; Papp, Z.; Zbiljić, J.; Vajdle, O.; Rodić, M. Bismuth Modified Carbon-Based Electrodes for the Determination of Selected Neonicotinoid Insecticides. Molecules 2011, 16, 4451-4466. https://doi.org/10.3390/molecules16064451
Guzsvány V, Papp Z, Zbiljić J, Vajdle O, Rodić M. Bismuth Modified Carbon-Based Electrodes for the Determination of Selected Neonicotinoid Insecticides. Molecules. 2011; 16(6):4451-4466. https://doi.org/10.3390/molecules16064451
Chicago/Turabian StyleGuzsvány, Valéria, Zsigmond Papp, Jasmina Zbiljić, Olga Vajdle, and Marko Rodić. 2011. "Bismuth Modified Carbon-Based Electrodes for the Determination of Selected Neonicotinoid Insecticides" Molecules 16, no. 6: 4451-4466. https://doi.org/10.3390/molecules16064451