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Molecules 2009, 14(6), 2032-2042; doi:10.3390/molecules14062032
Article

The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions

Department of Chemistry, Faculty of Science and Art, Adıyaman University, 02040 Adıyaman, Turkey
Received: 13 May 2009 / Revised: 27 May 2009 / Accepted: 3 June 2009 / Published: 5 June 2009
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Abstract

Novel 1,3-dialkylperhydrobenzimidazolinium chloride salts were prepared as precursors of N-heterocyclic carbenes 3a-e by reacting N,N’-dialkylcyclohexandiamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)2 and 3 have been tested as catalysts in homogenous Heck and Suzuki reactions.
Keywords: Heck and Suzuki reactions; perhydrobenzimidazolinium salt; palladium; carbene; catalyst Heck and Suzuki reactions; perhydrobenzimidazolinium salt; palladium; carbene; catalyst
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Yiğit, M. The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions. Molecules 2009, 14, 2032-2042.

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