Molecules 2009, 14(6), 2032-2042; doi:10.3390/molecules14062032
Article

The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions

Murat Yiğitemail
Department of Chemistry, Faculty of Science and Art, Adıyaman University, 02040 Adıyaman, Turkey
Received: 13 May 2009; in revised form: 27 May 2009 / Accepted: 3 June 2009 / Published: 5 June 2009
PDF Full-text Download PDF Full-Text [202 KB, uploaded 5 June 2009 13:45 CEST]
Abstract: Novel 1,3-dialkylperhydrobenzimidazolinium chloride salts were prepared as precursors of N-heterocyclic carbenes 3a-e by reacting N,N’-dialkylcyclohexandiamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)2 and 3 have been tested as catalysts in homogenous Heck and Suzuki reactions.
Keywords: Heck and Suzuki reactions; perhydrobenzimidazolinium salt; palladium; carbene; catalyst

Article Statistics

Click here to load and display the download statistics.

Cite This Article

MDPI and ACS Style

Yiğit, M. The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions. Molecules 2009, 14, 2032-2042.

AMA Style

Yiğit M. The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions. Molecules. 2009; 14(6):2032-2042.

Chicago/Turabian Style

Yiğit, Murat. 2009. "The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions." Molecules 14, no. 6: 2032-2042.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert