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Molecules 2009, 14(6), 2032-2042; doi:10.3390/molecules14062032
Article

The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions

Received: 13 May 2009; in revised form: 27 May 2009 / Accepted: 3 June 2009 / Published: 5 June 2009
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Abstract: Novel 1,3-dialkylperhydrobenzimidazolinium chloride salts were prepared as precursors of N-heterocyclic carbenes 3a-e by reacting N,N’-dialkylcyclohexandiamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)2 and 3 have been tested as catalysts in homogenous Heck and Suzuki reactions.
Keywords: Heck and Suzuki reactions; perhydrobenzimidazolinium salt; palladium; carbene; catalyst Heck and Suzuki reactions; perhydrobenzimidazolinium salt; palladium; carbene; catalyst
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Yiğit, M. The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions. Molecules 2009, 14, 2032-2042.

AMA Style

Yiğit M. The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions. Molecules. 2009; 14(6):2032-2042.

Chicago/Turabian Style

Yiğit, Murat. 2009. "The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions." Molecules 14, no. 6: 2032-2042.


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