Molecules 2009, 14(11), 4312-4325; doi:10.3390/molecules14114312
Article

Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent

1,* email, 1, 2 and 2
Received: 3 September 2009; in revised form: 13 October 2009 / Accepted: 22 October 2009 / Published: 26 October 2009
(This article belongs to the Special Issue Ferrocenes)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The C2-symmetrical “salen” ligand (+)-9 bearing two [5]ferrocenophane substituents has been prepared in five steps starting from readily available diacetylferrocene, p-hydroxybenzaldehyde and (R,R)-N,N’-diphenylethylenediamine. Reaction of (+)-9 with Mn(OAc)3, Co(OAc)2 ZnEt2 or UO2(OAc)2 gave the corresponding metal-complexes which were characterised by spectroscopic methods.
Keywords: chiral salen ligands; [5]ferrocenophane; metal complexes; circular dichroism spectra
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MDPI and ACS Style

Patti, A.; Pedotti, S.; Ballistreri, F.P.; Sfrazzetto, G.T. Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent. Molecules 2009, 14, 4312-4325.

AMA Style

Patti A, Pedotti S, Ballistreri FP, Sfrazzetto GT. Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent. Molecules. 2009; 14(11):4312-4325.

Chicago/Turabian Style

Patti, Angela; Pedotti, Sonia; Ballistreri, Francesco P.; Sfrazzetto, Giuseppe T. 2009. "Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent." Molecules 14, no. 11: 4312-4325.


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