The Synthesis of 1-(4-Triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, a Novel Trialkoxysilane Monomer for the Preparation of Functionalized Sol-gel Matrix Materials

doi:10.3390/molecules13102601

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Molecules 2008, 13(10), 2601-2607; doi:10.3390/molecules13102601

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The Synthesis of 1-(4-Triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, a Novel Trialkoxysilane Monomer for the Preparation of Functionalized Sol-gel Matrix Materials

Christopher J. Peeples, Raghu Ram Earni and John C. DiCesare*

800 South Tucker Drive, Department of Chemistry and Biochemistry, The University of Tulsa, Tulsa, Oklahoma, 74104, USA

* Author to whom correspondence should be addressed.

Received: 23 September 2008; in revised form: 3 October 2008 / Accepted: 7 October 2008 / Published: 20 October 2008

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Abstract: The title compound, 1-(4-triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, was synthesized in a three-step sequence starting from 2-(4-bromophenyl)propene. Containing both a trialkoxysilyl and a substituted 1,3-butanedione functional grouping within its structure, this new silane is a viable starting material for the preparation of functionalized sol-gel materials.

Keywords: Trialkoxysilane; 4; 4; 4-Trifluoro-1-phenyl-1; 3-butanedione (4-TPB); Sol-gel; Molecular imprinting

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MDPI and ACS Style

Peeples, C.J.; Earni, R.R.; DiCesare, J.C. The Synthesis of 1-(4-Triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, a Novel Trialkoxysilane Monomer for the Preparation of Functionalized Sol-gel Matrix Materials. Molecules 2008, 13, 2601-2607.

AMA Style

Peeples CJ, Earni RR, DiCesare JC. The Synthesis of 1-(4-Triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, a Novel Trialkoxysilane Monomer for the Preparation of Functionalized Sol-gel Matrix Materials. Molecules. 2008; 13(10):2601-2607.

Chicago/Turabian Style

Peeples, Christopher J.; Earni, Raghu R.; DiCesare, John C. 2008. "The Synthesis of 1-(4-Triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, a Novel Trialkoxysilane Monomer for the Preparation of Functionalized Sol-gel Matrix Materials." Molecules 13, no. 10: 2601-2607.

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