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Molecules 2007, 12(4), 861-867; doi:10.3390/12040861

C(aryl)-O Bond Formation from Aryl Methanesulfonates via Consecutive Deprotection and SNAr Reactions with Aryl Halides in an Ionic Liquid

College of Science, Northwest A and F University, Yangling 712100, P.R. China
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Received: 28 March 2007 / Revised: 19 April 2007 / Accepted: 20 April 2007 / Published: 30 April 2007
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Abstract

An efficient K3PO4-mediated synthesis of unsymmetrical diaryl ethers using the ionic liquid [Bmim]BF4 (1-butyl-3-methylimidazolium tetrafluoroborate) as solvent has been developed. The procedure involves consecutive deprotection of aryl methane-sulfonates and a nucleophilic aromatic substitution (SNAr) with activated aryl halides.
Keywords: C(aryl)-O bond; aryl methanesulfonates; nucleophilic aromatic substitution; diaryl ethers; ionic liquid C(aryl)-O bond; aryl methanesulfonates; nucleophilic aromatic substitution; diaryl ethers; ionic liquid
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Xu, H.; Chen, Y. C(aryl)-O Bond Formation from Aryl Methanesulfonates via Consecutive Deprotection and SNAr Reactions with Aryl Halides in an Ionic Liquid. Molecules 2007, 12, 861-867.

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