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An Aromatic Iodination Method, with Iodic Acid Used as the Only Iodinating Reagent†
Molecules 2005, 10(2), 401-406; doi:10.3390/10020401
Article

A Comparison of Microwave-Accelerated and Conventionally Heated Iodination Reactions of Some Arenes and Heteroarenes, Using ortho-Periodic Acid as the Oxidant†

 and *
Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, 1 Banacha Street, PL 02-097 Warsaw, Poland
* Author to whom correspondence should be addressed.
Received: 8 November 2004 / Revised: 18 November 2004 / Accepted: 18 November 2004 / Published: 28 February 2005
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Abstract

A fast and simple method for the oxidative iodination of some activated arenes and heteroarenes, either under microwave irradiation or by conventional heating, is reported, using diiodine and ortho-periodic acid as the oxidant. The reactions were carried out in hot 95% ethanol under a reflux condenser. For the microwave assisted reactions, the reaction times were always notably shortened, but the yields were nearly the same as those afforded by the conventional method.
Keywords: Oxidation; ortho-periodic acid as oxidant; oxidative iodination of activated arenes and heteroarenes; diiodine; microwave irradiation Oxidation; ortho-periodic acid as oxidant; oxidative iodination of activated arenes and heteroarenes; diiodine; microwave irradiation
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Sosnowski, M.; Skulski, L. A Comparison of Microwave-Accelerated and Conventionally Heated Iodination Reactions of Some Arenes and Heteroarenes, Using ortho-Periodic Acid as the Oxidant†. Molecules 2005, 10, 401-406.

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