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Synthesis of Unsymmetrical Annulated 2,2’-Bipyridine Analogues with Attached Cycloalkene and Piperidine Rings via Sequential Diels-Alder Reaction of 5,5’-bi-1,2,4-triazines†
Molecules 2005, 10(1), 274-278; doi:10.3390/10010274
Article

A Direct Route to 6,6’-Disubstituted-2,2’-Bipyridines by Double Diels-Alder/retro Diels-Alder Reaction of 5,5’-bi-1,2,4-Triazines

Institute of Chemistry, University of Podlasie, Poland
Received: 5 September 2004 / Revised: 3 January 2005 / Accepted: 3 January 2005 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract

Inverse electron demand Diels-Alder reaction of functionalized 5,5’-bi-1,2,4- triazines with bicyclo[2.2.1]hepta-2,5-diene in boiling p-cymene leads to a range of 6,6’- disubstituted-2,2’-bipyridines in good yield.
Keywords: 5; 5’-bi-1; 2; 4-triazines; norbornadiene; Diels-Alder reaction 5; 5’-bi-1; 2; 4-triazines; norbornadiene; Diels-Alder reaction
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Branowska, D. A Direct Route to 6,6’-Disubstituted-2,2’-Bipyridines by Double Diels-Alder/retro Diels-Alder Reaction of 5,5’-bi-1,2,4-Triazines. Molecules 2005, 10, 274-278.

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