Enantioselective Synthesis, Enantiomeric Separations and Chiral Recognition

doi:10.3390/books978-3-03936-239-4

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Enantioselective Synthesis, Enantiomeric Separations and Chiral Recognition

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July 2020

346 pages

ISBN978-3-03936-238-7 (Hardback)
ISBN978-3-03936-239-4 (PDF)

https://doi.org/10.3390/books978-3-03936-239-4

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This book is a reprint of the Special Issue Enantioselective Synthesis, Enantiomeric Separations and Chiral Recognition that was published in

Chemistry & Materials Science

Medicine & Pharmacology

Summary

This book includes both fundamental studies and applications in a multidisciplinary research field involving a high diversity of chiral compounds, including commercial substances with industrial applications, pharmaceuticals, and new chiral compounds with promising biological activities.

Recent developments and innovative approaches to producing enantiomerically pure compounds of industrial and research interest are included. Enantiomeric separation in both the analytical and preparative scale, determination of the enantiomeric purity, insights into enantioselective synthesis and many different aspects of chiral recognition, including chiral sensors, recognition in biological systems, and in analytical methods, are presented.

Original research and review articles show the broad scope of chirality in diverse analytical fields and the connection to enantioselective synthesis and biological activities.

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Keywords

metal-mediated molecular imprinting; hydrophilic template; atenolol; chiral separation; β-blockers; molecularly imprinted polymers; molecular recognition; chiral sulfoxide drugs; enantiomer elution order; electronic circular dichroism; quantum chemical calculation; molecular docking; crystallization; vaporization; purification; phenylglycinol; drug transporter; enantioselectivity; transport; inhibition; pharmacokinetics; chlorine interactions; 4-chloromandelic acid; benzyl-1-phenylethylamine; chiral discrimination; resolution; amino acid; phosphonate cavitand; molecular recognition; X-ray structure; host-guest chemistry; lysine; arginine; histidine; enantioselective potentiometric sensor; 2-amino-1-butanol; chiral porous organic cage; CC3-R; PVC membrane electrode; antitumor; neuroprotection; quinazolinones; fiscalin B; fumiquinazoline; enantioselectivity; multicomponent reactions; epoxides; aziridine; asymmetric synthesis; green synthesis; synthetic xanthones; chiral derivatives of xanthones; bioactivities; enantioselectivity; enantiomeric purity; chiral chromatography; chiral recognition; intermolecular interactions; chiral drugs; Whelk-O1 column; mobile phase additives; colistin sulfate; enantioselective; encapsulation; capillary chromatography; monolith; organic polymer; semiconductor nanowires; chirality; enantioselectivity; near-field optical chirality; liquid chromatography; enantioseparation; chiral stationary phase; chiral selector; chromatographic support; cis-epoxysuccinate hydrolase; tartaric acid; enantioselectivity; stereoselectivity; regioselectivity; epoxide hydrolase; immobilization; whole cell catalyst; enzyme stability; biocatalyst; (S)-(−)-perillaldehyde; Ammodaucus leucotrichus; amines; hemi-synthesis; essential oil; 2D NMR; single-crystal X-ray diffraction; chiral-HPLC; chirality; racemic mixture; enantiomer; enantiomeric recognition; enantiomeric separation; surface-modified nanoparticle; chiral ligand; chiral liquid crystals; optical purity; chiral separation; supercritical fluid chromatography; enantioseparation of liquid crystals; mass spectrometry detection; mesomorphic properties; Chiralpak^® ID-U; Chiralpak^® IG-U; mobile phase modifiers; polar organic and reversed phase modes; sub-2 μm particles; n/a