Reprint

Metal Complexes Containing Boron Based Ligands

Edited by
October 2019
110 pages
  • ISBN978-3-03921-584-3 (Paperback)
  • ISBN978-3-03921-585-0 (PDF)

This book is a reprint of the Special Issue Metal Complexes Containing Boron Based Ligands that was published in

Chemistry & Materials Science
Summary

Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.    

Format
  • Paperback
License
© 2019 by the authors; CC BY-NC-ND license
Keywords
boron-containing heterocycles; thiolato ligand; borinane; metallaborane; soft scorpionate; zinc; hexanuclear compounds; boron; carborane; carboranylamidinate; germanium; antimony; crystal structure; dodecaborate(6−); hexaborate(2−); oxidoborate; polyborate; self-assembly; X-ray structure; zinc(II) complex; nido-carborane; iron bis(dicarbollide); cobalt bis(dicarbollide); dimethyloxonium derivatives; methoxy derivatives; synthesis; properties; boron; iridium; pincer; carbodiphosphorane; metallacarborane; ruthenium; aggregation; UV-Vis spectroscopy; NTA; scorpionate; copper; borohydride; ligand; sulfur