Reprint

Homogeneous Catalysis and Mechanisms in Water and Biphasic Media

Edited by
February 2019
158 pages
  • ISBN978-3-03897-584-7 (Paperback)
  • ISBN978-3-03897-585-4 (PDF)

This book is a reprint of the Special Issue Homogeneous Catalysis and Mechanisms in Water and Biphasic Media that was published in

Chemistry & Materials Science
Engineering
Summary

In recent years, water phase chemistry and catalysis has witnessed a renewed interest, also in view of increasing environmental and economical concerns. Novel approaches, materials, and catalysts have been designed, for example, to convey the properties of known transition metal catalysts to their water-soluble analogs, reaching high activities and selectivities. This was possible thanks to new synthetic pathways to molecular catalysts, new mechanistic insights into the role of water as a non-innocent solvent, the use of theoretical methods and advanced engineering techniques, and the application of novel concepts for phase transfer agents in biphasic catalysis.

The book contains three review articles and six research articles, addressing topics related to water phase chemistry and catalysis, ranging from the use of cyclodextrins as mass transfer agents in biphasic catalysis, to water-soluble catalyst design for targeted chemical transformation, to the application of ultrasonic monitoring of biocatalysis in water, covering aspects such as chemical synthesis, various aspects of catalysis, and engineering solutions. The range of topics addressed in this book will stimulate the reader’s interest and provide a valuable source of information for researchers in academia and industry.

Format
  • Paperback
License
© 2019 by the authors; CC BY-NC-ND license
Keywords
chitosan aerogel; aldol reaction; water; isatin; catalysis; cyclodextrins; supramolecular chemistry; advanced oxidation technologies; bismuth oxybromide; carbamazepine; peroxide; toxicity; aqueous catalysis; alkynes; carboxylic acids; alkynoic acids; hydrocarboxylation reactions; cycloisomerization reactions; enol esters; lactones; β-oxo esters; ultrasonic spectroscopy; HR-US; ultrasonic velocity; ultrasonic attenuation; biocatalysis; enzymes; metal surface catalysis; degree of polymerization; average molar mass; microemulsions; formic acid; dehydrogenation; dehydration; ruthenium; carbon monoxide; preferential oxidation; PROX; ribozyme; DNAzyme; rate constant; melting temperature; molecular crowding; polyethylene glycol; acetylene dimerization; selectivity; performance; monovinylacetylene; iminodiacetic acid-modified Nieuwland catalyst; 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane; water-soluble phosphines; ruthenium arene complexes; ketone and imine transfer hydrogenation; aqueous phase catalysis; n/a