Anodic oxidation is an easy and cheap surface treatment to form nanostructures on the surface of titanium items for improving the interaction between metallic implants and the biological environment. The long-term success of the devices is related to their stability. In this work, titanium nanotubes were formed on a dental screw, made of titanium CP2, through an anodization process using an “organic” solution based on ethylene glycol containing ammonium fluoride and water. Then, the electrochemical stability in the Hank’s solution of these “organic” nanotubes has been investigated for 15 days and compared to that of titanium nanotubes on a similar type of sample grown in an inorganic solution, containing phosphoric and hydrofluoridric acids. Morphological and crystallographic analysis were performed by using scanning electron microscopy (SEM) and X-Ray diffractometry (XRD) tests. Electrochemical measurements were carried out to study the stability of the nanotubes when are in contact with the biological environment. The morphological measurements revealed long nanotubes, small diameters, smooth side walls, and a high density of “organic” nanotubes if compared to the “inorganic” ones. XRD analysis demonstrated the presence of rutile form. An appreciable electrochemical stability has been revealed by Electrochemical Impedance Spectroscopy (EIS) analysis, suggesting that the “organic” nanotubes are more suitable for biomedical devices. Full article

Tungsten (W) is currently deemed the main candidate for the plasma-facing armor material of the first wall of future fusion reactors, such as DEMO. Advantages of W include a high melting point, high thermal conductivity, low tritium retention, and low erosion yield. However, was an accident to occur, air ingress into the vacuum vessel could occur and the temperature of the first wall could reach $1200\mathrm{K}$ to $1450\mathrm{K}$ due to nuclear decay heat. In the absence of cooling, the temperature remains in that range for several weeks. At these temperatures, the radioactive tungsten oxidizes and then volatilizes. Smart W alloys are therefore being developed. Smart alloys are supposed to preserve properties of W during plasma operation while suppressing tungsten oxide formation in case of an accident. This study focuses on investigations of thin film smart alloys produced by magnetron sputtering. These alloys provide an idealistic system with a homogeneous distribution of the elements W, chromium (Cr), and yttrium (Y) on an atomic scale. The recommended composition is W with 12 weight % of Cr and $0.5$ weight % of Y. Passivation and a suppression of WO₃ sublimation is shown. For the first time, the mechanisms yielding the improved oxidation resistance are analyzed in detail. A protective Cr₂O₃ layer forms at the surface. The different stages of the oxidation processes up to the failure of the protective function are analyzed for the first time. Using ¹⁸O as a tracer, it is shown for the first time that the oxide growth occurs at the surface of the protective oxide. The Cr is continuously replenished from the bulk of the sample, including the Cr-rich phase which forms during exposure at $1273\mathrm{K}$. A homogenous distribution of yttria within the W-matrix, which is preserved during oxidation, is a peculiarity of the analyzed alloy. Further, an Y-enriched nucleation site is found at the interface between metal and oxide. This nucleation sites are deemed to be crucial for the improved oxidation resistance. Full article

The present manuscript aims to determine the effect of various deformation levels during low-temperature thermo-mechanical treatment (LTTT) on the microstructure and fatigue strength of Zr-microalloyed Al-Zn-Mg alloy. The fatigue strength of the alloy was studied in high-cycle bending-torsion tests. The determination of the influence of plastic deformation level during LTTT on the microstructure was based on transmission electron microscopy (TEM) observations. The analysis of fracture after the fatigue tests was performed based on fractographic images using scanning electron microscopy (SEM). It was found that the major factor affecting the microstructure of the alloy, and determining the nature of fatigue fracture, is the strain level applied during LTTT. Full article

As an important index of weld quality, the weld bead geometry is closely related to the welding process parameters (WPP). Therefore, it is crucial to establish the relationships between the WPP and weld bead shape to serve as an indicator of the weld quality. However, it is difficult to predict the weld bead shape accurately due to uncertainty. In this paper, laser keyhole welding (LKW) experiments are conducted on 2205 stainless steel at sample points generated by the optimal Latin hypercube sampling (OLHS). Then the relationships between WPP and weld width (WW) are constructed using stochastic kriging model (SKM), considering the randomness of the welding process. To verify the effectiveness of the SKM, two validation approaches, the additional experiments validation and k-fold cross-validation, are used to compare the prediction performance of SKM and the traditional kriging model. SKM is superior to the kriging model at the whole five additional test points with smaller relative error. As to k-fold cross-validation, SKM provides a smaller root mean square error at four in five groups of the data. In addition, SKM can provide the variations of the entire weld bead shape. Overall, the SKM is very prominent in predicting the weld bead shape, considering fluctuations of WPP. Full article

In this study, a Ti composite reinforced with 5 vol. % (TiB_w + TiC_p) was fabricated by an in situ casting route. Open die forging in (α + β) phase region was conducted on the composite casting. The microstructures of the as-forged composite pancake are inhomogeneous in terms of matrix microstructure and distribution of reinforcements. The matrix grains are gradually refined from the periphery to centre of the pancake. The reinforcements TiB_w and TiC_p tend to be uniformly distributed in the centre region. It is suggested that the microstructure difference can be mainly ascribed to the temperature variation from the periphery to the centre. The tensile testing results show that the centre region of the composite pancake exhibits higher strength than the peripheral region. The mechanical behaviour of the composite pancake with the temperature is discussed. Full article

An advanced bainite rail with high strength–toughness combination was produced in a steel mill and the effects of tempering on the microstructure and properties of the bainite rail steel were investigated by optical microscopy, transmission electron microscopy, electron back-scattering diffraction and X-ray diffraction. Results indicate that the tensile strength, elongation and impact toughness were about 1470 MPa, 14.5% and 83 J/cm², respectively, after tempering at 400 °C for 200 min. Therefore, a high-strength bainite rail steel with good toughness was developed. In addition, the amount of retained austenite (RA) decreased due to bainite transformation after low-temperature tempering (300 °C) and RA almost disappeared after high-temperature tempering (500 °C). Moreover, as the tempering temperature increased, the tensile strength of the rail head first decreased due to the decreased dislocation density and carbon content in bainite ferrite and the coarseness of bainite ferrite, and then increased because of carbide precipitation at high-temperature tempering. Furthermore, RA played a significant role in the toughness of bainite rail. The elongation and toughness of the rail obviously decreased after tempering at 500 °C for 200 min because of the disappearance of RA and appearance of carbides. Full article

As having an important part of coordination control in steelmaking process, traditional production planning and scheduling technologies are developed with little consideration of the metallurgy mechanism, leading to lower feasibility for actual production. Based on current situation and requirements of steel plants, this paper focuses on the investigation of the charge plan from the view of metallurgy and establishes a charge planning model concerning the minimization of both the open order amount and the difference in due dates of the orders in each charge. A modified multi-objective evolutionary algorithm is proposed to solve the charge planning model of steelmaking process. By presenting a new fitness function, based on the rule of target ranking and introducing the Elitism strategy to construct the non-inferior solution set, the quality of solutions is improved effectively and the convergence of the algorithm is enhanced remarkably. Simulation experiments are carried out on the orders from actual production, and the proposed algorithm produces a group of optimized charge plans in a short time. The quality of the solutions is better than those produced by a genetic algorithm, modified partheno-genetic algorithm, and those produced manually to some extent. The simulation results demonstrate the feasibility and effectiveness of the proposed model and the algorithm. Full article

Based on first principles calculations, we theoretically predict the new two-dimensional (2D) MgH₂. The thermodynamic stability, partial density of states, electron localization function, and Bader charge of pure and the transition metal (Ti, V, and Mn) doped 2D MgH₂ are investigated. The results show that all the systems are dynamically stable, and the dehydrogenation properties indicate that the decomposition temperature can be reduced by introducing the transition metal, and the Mn doped system exhibits good performance for better hydrogen storage and dehydrogenation kinetics. Full article

This study designed (Ti_0.55Cu_0.20Zr_0.15Ni_0.10)_1−xSi_x amorphous alloys based on binary deep eutectics and examined the effect of silicon (Si) on the amorphous forming ability of the filler alloys. The results show that a certain amount of Si added to the filler metals could improve the amorphous forming ability of the alloys. Under the same experimental conditions, the Ti_0.55Cu_0.20Zr_0.15Ni_0.10 filler metal with 0.5 wt % Si had the strongest amorphous forming ability compared to the other filler alloys containing different amounts of Si; its reduced glass transition temperature (T_rg) was 0.5554, and its supercooled liquid phase region width (∆T_x) reached 60 °C. The (Ti_0.55Cu_0.20Zr_0.15Ni_0.10)_99.5%Si_0.5% filler metal designed in these experiments presented good amorphous forming ability and wettability. The brazed joint of SiC and TC4 obtained with this amorphous filler metal showed a shear strength of 102 MPa, indicating an increase of 122% compared to the brazed joint obtained with the filler metal without Si. Full article

The forging of sintered aluminum powder metallurgy alloys is currently viewed as a promising industrial technology for the manufacture of complex engineered products. The powder metallurgy process facilitates the use of admixed ceramic particles to produce aluminum metal matrix composites. However, fundamental data on the thermal-mechanical response of commercially relevant powder metallurgy alloy systems under varying conditions of temperature and strain rate are lacking. To address this constraint, the current study investigates the thermal-mechanical processing response of a family of metal matrix composite materials that employ a commercially exploited base alloy system coupled with admixed additions of aluminum nitride. Industrially-sintered compacts were tested under hot compression using a Gleeble 3500 thermal-mechanical test system to quantify their flow behavior. The nominal workability was assessed as a function of material formulation, sintered preform condition, and processing parameters (temperature and strain rate). Optical metallography and electron backscatter diffraction were used to observe the grain evolution through deformation. Full densification was achieved for materials with ceramic concentrations of 2% volume or less. Zener-Hollomon constituent analyses were also completed to elucidate a more comprehensive understanding the flow behavior inherent to each material. Flow behavior varied directly with the sintered density, which was influenced by the concentration and nature of ceramic particulate. Full article

The fatigue resistance of coarse-grained (CG) metals can be greatly improved by introducing a nanograined surface layer. In this study, the Weibull distribution is used to characterize the spatially-random fracture properties of specimens under axial fatigue. For the cylindrical solid specimen, the heterogeneity of element sizes may lead to unfavorable size effects in fatigue damage initiation and evolution process. To alleviate the size effects, a three-dimensional cohesive finite element method combined with a local Monte Carlo simulation is proposed to analyze fatigue damage evolution of solid metallic specimens. The numerical results for the fatigue life and end displacement of CG specimens are consistent with the experimental data. It is shown that for the specimens after surface mechanical attrition treatment, damage initiates from the subsurface and then extends to the exterior surface, yielding an improvement in the fatigue life. Good agreement is found between the numerical results for the fatigue life of the specimens with the nanograined layer and experimental data, demonstrating the efficacy and accuracy of the proposed method. Full article

An in situ scanning electron microscope (SEM) study was conducted on a super duplex stainless steel (SDSS) containing 0%, 5% and 10% $\sigma$-phase. The material was heat treated at 850 °C for 12 min and 15 min, respectively, to achieve the different amounts of $\sigma$-phase. The specimens were investigated at room temperature and at −40 °C. The microstructure evolution during the deformation process was recorded using electron backscatter diffraction (EBSD) at different strain levels. Both $\sigma$-phase and $\chi$-phase were observed along the grain boundaries in the microstructure in all heat treated specimens. Cracks started to form after 3–4% strain and were always oriented perpendicular to the tensile direction. After the cracks formed, they were initially arrested by the matrix. At later stages of the deformation process, cracks in larger $\sigma$-phase constituents started to coalesce. When the tensile test was conducted at −40 °C, the ductility increased for the specimen without $\sigma$-phase, but with $\sigma$-phase present, the ductility was slightly reduced. With larger amounts of $\sigma$-phase present, however, an increase in tensile strength was also observed. With $\chi$-phase present along the grain boundaries, a reduction of tensile strength was observed. This reduction seems to be related to $\chi$-phase precipitating at the grain boundaries, creating imperfections, but not contributing towards the increase in strength. Compared to the effect of $\sigma$-phase, the low temperature is not as influential on the materials performance. Full article

A new special structural nickel-based alloy for use in molten fluoride salt environments in molten salt reactors (MSR) began to be developed by the COMTES FHT Company in the Czech Republic as early as 2001. The outcome of this development was the MoNiCr alloy, an alternative to Hastelloy-N. The present study was carried out on two experimentally-manufactured nickel alloys: MoNiCr and HN80MTY. Its purpose was to activate recrystallization processes in the as-cast microstructure of these alloys. In addition, experiments were performed to find a temperature which produces complete recrystallization. Static and dynamic recrystallization was studied in both alloys as well. An important aspect was to determine the lowest amount of deformation which still ensures complete recrystallization and provides as uniform recrystallized grains as possible. Such microstructure is well-suited for subsequent forming operations. Specimen microstructures were characterized using light microscopy (LM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and electron backscatter diffraction (EBSD). Furthermore, corrosion tests of the MoNiCr alloy were conducted. Full article

The microstructure and mechanical properties of cold-rolled Fe-18Mn-3Al-3Si-0.03C transformation induced plasticity/twinning induced plasticity (TRIP/TWIP) steel in the temperature range of 25 to 600 °C were studied. The experimental steel exhibited a good combination of ultimate tensile strength (UTS) of 905 MPa and total elongation (TEL) of 55% at room temperature. With the increase of deformation temperature from 25 to 600 °C, the stacking fault energy (SFE) of the experimental steel increased from 14.5 to 98.8 mJm⁻². The deformation mechanism of the experimental steel is controlled by both the strain induced martensite formation and strain induced deformation twinning at 25 °C. With the increase of deformation temperature from 25 to 600 °C, TRIP and TWIP effect were inhibited, and dislocation glide gradually became the main deformation mechanism. The UTS decreased monotonously from 905 to 325 MPa and the TEL decreased (from 55 to 36%, 25–400 °C) and then increased (from 36 to 64%, 400–600 °C). The change in mechanical properties is related to the thermal softening effect, TRIP effect, TWIP effect, DSA, and dislocation slip. Full article

Global industrial adoption of laser-based powder bed fusion (LPBF) technology is still limited by the production speed, the size of the build envelope, and therefore the maximum part size that can be produced. The cost of LPBF can be driven down further by improving the build rates without compromising structural integrity. A common approach is that the build rate can be improved by increasing the laser power and beam diameter to instantly melt a large area of powder, thus reducing the scanning time for each layer. The aim of this study was to investigate the aspects of upscaling LPBF processing parameters on the characteristic formation of stable single tracks, which are the primary building blocks for this technology. Two LPBF systems operating independently, using different parameter regimes, were used to produce the single tracks on a solid substrate deposited with a thin powder layer. The results obtained indicate that higher laser power and spot size can be used to produce stable tracks while the linear energy input is increased. It was also shown statistically that the geometrical characteristics of single tracks are mainly affected by the laser power and scanning speed during the scanning of a thin powder layer. Full article