Long-term deterioration and durability concerns in harsh environments with acidic attacks are considered as the weaknesses of ordinary Portland cement (OPC) concrete. Although the performance of alkali-activated slag concrete (AASC) has been reported to be superior in acidic environments, there is a poor understanding regarding the impacts of diverse mix design parameters on AASC durability in an acidic environment. This research aims to understand the impact of mix design parameters on the durability of AASC in the sulfuric acid (H₂SO₄) environment with pH = 3. The type of alkaline solution, the molarity of alkaline solutions, the weight ratio of alkaline solutions to slag, and the weight ratio of NaOH to Na₂SiO₃ are mix design parameters investigated in this study. The compressive strength reduction and weight loss were monitored from early ages up to 180 days. Moreover, an OPC concrete sample was produced as a reference. Full article

Reinforced concrete structures, particularly in cold areas, experience early deterioration due to steel corrosion. Fiber-Reinforced Concrete (FRC) is an emerging construction material and cost-effective substitute for conventional concrete to enhance the durability and resistance against crack development. This article examines the structural performance of hybrid ferro fiber reinforced concrete slabs (mix ratio of mortar 1:2) comprising silica fume, layers of spot-welded mesh and different ratios of polypropylene fibers. The ferrocement slabs are compared with a conventional Reinforced Cement Concrete (RCC) slab (mix ratio of 1:2:4). The experimental work comprised a total of 13 one-way slabs, one control specimen and three groups of ferrocement slabs divided based on different percentages of Poly Propylene Fibers (PPF) corresponding to 0.10%, 0.30% and 0.50% dosage in each group. Furthermore, in each group, the percentage of steel ratio in ferrocement slabs varied between 25% and 100% of the steel area in the reinforced concrete control slab specimen. For evaluating the structural performance, the observation of deflection, stress-strain behavior, cracking load and energy absorption are critical parameters assessed using LVDTs and strain gauges. At the same time, the slabs were tested in flexure mode with third point loading. The experimental results showed that the first cracking load and ultimate deflection for fibrous specimens with 0.5% fiber and 10% silica fume increased by 15.25% and 13.2% compared with the reference RCC control slab. Therefore, by increasing the percentage of PPF and steel wire mesh reinforcement in the ferrocement slab, the post-cracking behavior in terms of deflection properties and energy absorption capacity was substantially enhanced compared to the RCC control slab. Full article

Creep affects the long-term deformation of concrete structures. Nonlinear creep further overestimates the safety factor of structures and affects the safety service performance. The coupling of creep and a damage model considering the rate effect is conducive to accurate prediction of nonlinear creep, but the iterative process of strain makes the calculation method more complex. The purpose of this study is to propose a nonlinear creep explicit method that considers the damage evolution of concrete under compression. Two groups of axial compression members with compressive stresses of 0.2 fc and 0.4 fc were made. Considering the law of concrete damage evolution under uniaxial compression, coupled with elastic creep and damage incremental strain, the lower limit of the medium stress level that gives rise to nonlinear creep is analyzed. The concrete nonlinear creep amplification coefficient with a loading age of 28 days and loading duration of 360 days is studied with consideration for the uncertainty of relative humidity and the theoretical thickness of the component. On this basis, the explicit calculation formula of the nonlinear creep amplification coefficient related to the concrete axial compressive strength and stress level is given. The results indicate that the nonlinear creep amplification coefficient increases nonlinearly with an increase in the stress level, and, when the compressive stress level ratio is higher than 0.6, the nonlinear creep amplification coefficient increases significantly; when the stress level is determined, the creep amplification coefficient decreases gradually with an increase in the compressive strength of the concrete. It is suggested that a stress level range of 0.35~0.75 should be used for the study of a nonlinear creep amplification factor under the medium stress state. Full article

To explore the effect of different emulsifier contents on the stability performance of biomass-emulsified asphalt, three types of emulsified asphalt with 1%, 3%, and 5% anionic emulsifiers were prepared and analyzed by molecular dynamics simulation and macroscopic experiments. Firstly, we used molecular simulation software (Material Studio, MS) to construct a model of biomass-emulsified asphalt with different emulsifier contents and analyzed the microscopic mechanism of the emulsifier to improve the stability of the emulsified asphalt by the radial distribution function, interaction energy, interfacial layer thickness, and solubility parameters of the emulsified asphalt system with different emulsifier contents. The results were validated by macro and micro tests including storage stability, particle size determination, and infrared spectroscopy. The results show that at low emulsifier contents, the emulsifier can reduce the interfacial tension between the oil–water interface and expand the transition region between the two phases (interfacial layer thickness), which will prevent interparticle agglomeration and reduce the emulsion particle size, thus reducing the settling rate and ensuring the stability of the emulsion. When the emulsifier content is further increased beyond the critical micelle concentration, the emulsifiers will agglomerate with each other and show larger peaks in the radial distribution function, and the phenomenon of emulsifier agglomeration will appear in the five-day storage stability test, resulting in a corresponding decrease in the proximity of the infrared absorption peak area ratio in the same wavelength band of the upper and lower layers of the biomass-emulsified asphalt, and the emulsion stability decreases instead. Full article

The traditional method of removing ice and snow on roads carries the risk of damaging roads and the environment. In this circumstance, the technology of salt-storage asphalt pavement has gradually attracted attention. However, snow-melting salts may also have an impact on asphalt mixture performance. To explore the effect of snow-melting salts on the mechanical and surface properties of salt-storage asphalt mixtures (SSAM), SSAMs were prepared with styrene–butadiene–styrene (SBS)-modified asphalt and high-elastic asphalt (HEA) as binders and snow-melting salts as fillers. The influence of the type of asphalt binder and the content of snow-melting salt on the performance of the SSAM was preliminarily investigated through laboratory tests. The results show that the high-temperature, low-temperature, and moisture resistance performance of the SBS group SSAM decreased by 9.8–15.1%, 1.6–12.3%, and 6.3–19.4%, respectively, compared with SBS00. The higher the amount of snow-melting salt, the greater the performance drop. The three mechanical properties of the HEA group containing high-elastic agent TPS are 11.3–19.7%, 4.2–12.3%, and 4.8–13.3% higher than that of the SBS group. Even when the content of snow-melting salt is 50% or 75%, the mechanical properties of the HEA group are better than that of SBS00 without snow-melting salt. Snow-melting salt has clear advantages in improving the anti-skid performance but decreases the anti-spalling performance. The surface properties of the HEA group were also better than that of the SBS group. Considering the mechanical properties and surface properties, the comprehensive performance of the HEA group is better than that of the SBS group, and HEA50 has the best comprehensive performance. In addition, the construction performance of the SSAM has also been verified, and the production of SSAM according to the hot mix asphalt can meet the specification requirements. Full article

Cement clinkers containing mainly belite (β-C₂S as a model crystal), replacing alite, offer a promising solution for the development of environmentally friendly solutions to reduce the high level of CO₂ emissions in the production of Portland cement. However, the much lower reactivity of belite compared to alite limits the widespread use of belite cements. Therefore, this work presents a fundamental atomistic computational approach for comprehending and quantifying the mesoscopic forward dissolution rate of β-C₂S, applied to two reactive crystal facets of (100) and ($\overline{1}00$). For this, an atomistic kinetic Monte Carlo (KMC) upscaling approach for cement clinker was developed. It was based on the calculated activation energies (ΔG*) under far-from-equilibrium conditions obtained by a molecular dynamic simulation using the combined approach of ReaxFF and metadynamics, as described in the Part 1 paper in this Special Issue. Thus, the individual atomistic dissolution rates were used as input parameters for implementing the KMC upscaling approach coded in MATLAB to study the dissolution time and morphology changes at the mesoscopic scale. Four different cases and 21 event scenarios were considered for the dissolution of calcium atoms (Ca) and silicate monomers. For this purpose, the (100) and ($\overline{1}00$) facets of a β-C₂S crystal were considered using periodic boundary conditions (PBCs). In order to demonstrate the statistical nature of the KMC approach, 40 numerical realizations were presented. The major findings showed a striking layer-by-layer dissolution mechanism in the case of an ideal crystal, where the total dissolution rate was limited by the much slower dissolution of the silicate monomer compared to Ca. The introduction of crystal defects, namely cutting the edges at two crystal boundaries, increased the overall average dissolution rate by a factor of 519. Full article

Planting concrete, an eco-friendly concrete in which plants can grow directly, has been widely used in roof greening and the slopes of rivers. Porosity and compressive strength are important indicators for evaluating the properties of planting concrete. By preparing planting concrete with different aggregate gradations (10–30 mm, 20–40 mm) and water–cement ratios (0.25, 0.27, 0.29, 0.31, 0.33), the effect of aggregate gradation and water–cement ratio on the porosity and compressive strength of the planting concrete was analyzed, the intrinsic relationship between aggregate gradation and plane pore parameters was studied, the strength growth pattern and microscopic strengthening mechanism were studied, the relationship between porosity and compressive strength of the planting concrete were explored, and a tall fescue planting experiment was carried out to evaluate the plantation performance of the planting concrete. The results show that under the same conditions of water–cement ratio, the smaller the particle size of the aggregate, the smaller the porosity of the plane, and the denser the structure. The average diameter of the planting concrete shows an exponential relationship with the porosity of plane. The early growth of the compressive strength of the planting concrete is rapid; the compressive strength has a linear relationship at the ages of 7 days and 28 days. Compared to polynomial and logarithmic functions, the exponential function gives a better insight into the relationship between the porosity and compressive strength of the planting concrete. Tall fescue seeds germinate and grow well; height, cover, and leaf rootstock and element content of plants can be used as indicators to assess the performance of vegetated concrete planting. Full article

This study investigates the technological, thermal, mechanical, and technological properties of glass foams produced with soda-lime glass residues and rice husk ash sintered at 850–950 °C. The results for apparent density (0.28–0.30 g/cm³), porosity (82–87 ± 4%), compressive strength (1.18 ± 0.03–1.25 ± 0.03 MPa), and thermal conductivity (0.283–0.326 W/mK) are within the limits for commercial foams. The volumetric expansion potential and low thermal conductivity of the glass foams produced favor their use as thermal insulating materials in coat walls, thus improving thermal comfort in the construction sector. The results of X-ray fluorescence show that the foam glass is of the soda-lime type (SiO₂, Na₂O, and CaO), the rice husk ash is rich in SiO₂, CaO, Na₂O, Al₂O₃, K₂O and Fe₂O₃, and the calcium carbonate is rich in CaO. The glass foams produced in this study are promising because they present more economical and efficient manufacturing, resulting in lightweight materials with thermal insulating properties that can be used in the construction sector. These glass foams also reduce the consumption of natural and synthetic raw materials, adding value to the waste used in this study by transforming them into co-products, thus favoring the economic circulation of the region. Full article

To investigate the effects of limestone powder and gypsum on the early hydration of ye’elimite, the hydration behavior of C₄A₃$\overline{\mathrm{S}}$-LP-CaSO₄·2H₂O-H₂O systems are researched. The hydration behavior of systems are researched by employing isothermal calorimetry, XRD technique and chemical shrinkage. The thermodynamic modelling method is employed to predict the equilibrium phase assemblages. The results show that the system with 5 wt.% LP has a comparable hydration heat evolution to limestone powder-free systems. Limestone powder can take part in the reaction to produce monocarboaluminate in the system with M-value (molar ratio of gypsum to ye’elimite) of 1, but monocarboaluminate is not found in the system with M-value of 2. The level off time of chemical shrinkage shortens with the increase of limestone powder dosage. Thermodynamic modelling results show that monocarboaluminate is no longer formed in all systems when M-value exceeds 1.27, which corresponds to the XRD results. This study can provide theoretical guidance for the rational utilization of limestone powder in calcium sulphoaluminate cement. Full article

The reuse of steel slag, a large-scale solid waste from steel production, has good social and environmental benefits. The application of a steel slag asphalt mixture is mainly hindered by its volume expansion in water. The expansion of steel slag can be inhibited by oxalic acid. The expansion rate and adhesion of steel slag were investigated, and the immersion stability of steel slag and its asphalt mixture was evaluated by water erosion. By means of XRD, XRF, TG, SEM, etc., the influence mechanism of oxalic acid and water erosion on the properties of steel slag and its asphalt mixture was discussed. The results show that oxalic acid can not only inhibit the expansion of steel slag but also improve its crush resistance, with a reduction in the expansion rate of steel slag by 53%. Oxalic acid is able to leach alkaline metal elements, reducing its adhesion with asphalt. After 10 days of water erosion, the rutting stability and bending crack resistance of the treated steel slag mixture decreased by 37% and 43.2%, respectively. Calcium oxalate is generated on the surface of treated steel slag, which improves the surface compactness, effectively inhibits the expansion of steel slag caused by water erosion, and improves the performance of steel slag and its asphalt mixture. Water erosion can accelerate the hydration and shedding of calcium-containing substances on the surface of steel slag, reduce the adhesion of steel slag, and lead to degradation in the performance of steel slag and its asphalt mixture. Oxalic acid is able to effectively inhibit the expansion of steel slag, and the treated steel slag can be used as recycled aggregate in asphalt mixture, effectively solving the problems of road aggregate deficiency and environmental pollution caused by steel slag. Full article

Metaheuristic optimization techniques are widely applied in the optimal design of structural members. This paper presents the application of the harmony search algorithm to the optimal dimensioning of reinforced concrete circular columns. For the objective of optimization, the total cost of steel and concrete associated with the construction process were selected. The selected variables of optimization include the diameter of the column, the total cross-sectional area of steel, the unit costs of steel and concrete used in the construction, the total length of the column, and applied axial force and the bending moment acting on the column. By using the minimum allowable dimensions as the constraints of optimization, 3125 different data samples were generated where each data sample is an optimal design configuration. Based on the generated dataset, the SHapley Additive exPlanations (SHAP) algorithm was applied in combination with ensemble learning predictive models to determine the impact of each design variable on the model predictions. The relationships between the design variables and the objective function were visualized using the design of experiments methodology. Applying state-of-the-art statistical accuracy measures such as the coefficient of determination, the predictive models were demonstrated to be highly accurate. The current study demonstrates a novel technique for generating large datasets for the development of data-driven machine learning models. This new methodology can enhance the availability of large datasets, thereby facilitating the application of high-performance machine learning predictive models for optimal structural design. Full article

This study employed Taguchi-Grey relational analysis to optimize the influences of binder content, the molarity of sodium hydroxide (SH) solution, alkaline solution to binder content (Al/Bi) ratio, water to alkali-activated solids (W/S) ratio, and sodium silicate to sodium hydroxide solution (SS/SH) ratio on the workability, setting time, and compressive strength of alkali-activated slag-based concrete (AASC). Then, the recycled tire steel fibers (RTSF) were introduced into the optimized mixture in different dosages, and the physical and mechanical properties of fiber-reinforced AASC (FR-AASC) were evaluated. RTSF inclusion negatively affected the workability and increased the density while slightly reducing the water absorption. Additionally, the compressive strength and flexural behavior of FR-AASC improved by increasing the RTSF content. The analysis of images taken from flexural specimens through the Digital Image Correlation technique (DIC) revealed that higher RTSF dosage caused a curved macro crack with several branches alongside, leading to a better post-cracking performance in terms of strength and toughness. Full article

Annual coffee consumption has increased to 10 million tons. Of the coffee consumed, 65% is discarded as spent coffee grounds (SCG). However, most SCG are buried in the ground as organic waste. The more coffee consumption increases, the more land is used for disposing of spent coffee. SCG recycling has gotten considerable attention as a solution involved in these issues. The construction community has studied means and methods to recycle SCG as construction materials, such as bricks, subgrade fillers, thermal insulators, etc. This paper presents a new method, which recycles SCG as a construction material, maximally using its acidity. The SCG were hardened with natural binders (i.e., animal glue (AG) and starch (S)) and red clay (RC). The SCG mixtures were pressed with 2 MPa in a cylindrical mold and cured for 7 days. Then, the strength, durability, and pH tests were measured. The AG- and RC-treated SCG sample, which outputs 1933 kPa of strength and a 4.9 pH value, is identified as the optimal sampling method among the acid materials produced in this study. The optimal sample decreases the pH to approximately 7 of water where 68% weight of Ordinary Portland cement was soaked in. Full article

Due to increasingly stringent requirements, tapes and adhesive joints are a commonly used method to ensure tightness and energy efficiency in modern building envelopes. Previous studies have researched and tested properties such as the strength and tightness of adhesive joints. So far, water vapour resistance has been neglected. This article aims to determine the vapour resistance and shed light on possible consequences of vapour-tight adhesive joints in breather membranes used in roof assemblies. Laboratory measurements of vapour resistance were conducted according to NS-EN ISO 12572:2016, known as the cup method. Eleven products of breather membranes were tested. Results from the laboratory measurements were used to evaluate the impact of vapour-resistant adhesive joints related to the drying of built-in moisture. The simulation programs WUFI 2D and WUFI Mould Index VTT were used to model scenarios for moisture transport and risk for mould growth. Laboratory results show that the vapour resistance of breather membrane adhesive joints varies from 1.1 to 32 m in s_d-value. Three of the tested products have a vapour resistance larger than 10 m, while four products have an s_d-value less than 2.0 m. The s_d-values of the membranes themselves range between 0.027 and 0.20 m. All tested adhesive joints are considerably more vapour tight than the Norwegian recommended value for breather membranes (<0.5 m). However, the mould growth analysis shows that the risk of mould growth is low in most practical cases, except when using adhesive joints with the highest vapour resistance in roofs assembled during autumn. Full article

Polycarboxylate superplasticiser (PCE) is notably sensitive towards Na-Montmorillonite (Na-Mmt), an impurity generated from the manufacturing of concrete aggregate due to the chemical intercalation and poor surface adsorption. In order to improve the poor compatibility of PCE, the protein-based retarders were applied as the sacrificial agents, and its synergetic effects in cementitious materials containing Na-Mmt were investigated. The protein-based retarders were applied as the sacrificial agents and its synergetic effects in cementitious materials containing Na-Mmt were investigated. In addition to test rheology, minislump, and setting time, the adsorption behaviour and intercalation were characterised via Total Organic Carbon, X-ray photoelectron spectroscopy, and X-ray diffraction. The results revealed that the incorporation of protein-retarders improved the performance of PCE in terms of workability, and the rheological behaviour of cement with Na-Mmt. Moreover, compared to simultaneous addition, the application of separate addition further increased the workability and improved workability retention, with best dispersion performance obtained by prior adding the retarders, which could be due to the lessened intercalation between the layers of Na-Mmt. Full article