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Inorganics 2017, 5(4), 89; https://doi.org/10.3390/inorganics5040089

Lewis Base Complexes of Magnesium Borohydride: Enhanced Kinetics and Product Selectivity upon Hydrogen Release

1
Pacific Northwest National Laboratory, 902 Battelle Blvd, Richland, WA 99352, USA
2
Department of Chemistry, University of Hawaii at Manoa, 2545 McCarthy Mall, Honolulu, HI 96822, USA
*
Authors to whom correspondence should be addressed.
Received: 3 November 2017 / Revised: 27 November 2017 / Accepted: 28 November 2017 / Published: 6 December 2017
(This article belongs to the Special Issue Functional Materials Based on Metal Hydrides)
View Full-Text   |   Download PDF [809 KB, uploaded 6 December 2017]   |  

Abstract

Tetrahydofuran (THF) complexed to magnesium borohydride has been found to have a positive effect on both the reactivity and selectivity, enabling release of H2 at <200 °C and forms Mg(B10H10) with high selectivity. View Full-Text
Keywords: hydrogen storage; Lewis base adducts; borohydride hydrogen storage; Lewis base adducts; borohydride
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Chong, M.; Autrey, T.; Jensen, C.M. Lewis Base Complexes of Magnesium Borohydride: Enhanced Kinetics and Product Selectivity upon Hydrogen Release. Inorganics 2017, 5, 89.

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